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Tetrabutylammonium borohydride and its complex with aluminum borohydride

  • L. V. Titov
  • L. A. Gavrilova
  • E. R. Eremin
  • S. S. Mishchenchuk
  • V. Ya. Rosolovskii
Brief Communications

Conclusions

  1. 1.

    Tetrabutylammonium borohydride was obtained by the exchange reaction of tetrabutylammonium bromide with excess sodium borohydride in ether isopropyl alcohol or benzene medium.

     
  2. 2.

    Tetrabutylammonium borohydride aluminate, [(C4H9)4N] [Al(BH4)4], was synthesized by the reaction of the tetrabutylammonium and aluminum borohydrides.

     
  3. 3.

    In the series of complex hydrides, containing the anions BH 4 and [Al(BH4)4] and the cation [R4N]+, the solubility in nonpolar solvents increases in a steady manner, while the melting point decreases, with increase in the length of the hydrocarbon chain R.

     

Keywords

Benzene Hydrocarbon Hydride Isopropyl Alcohol Exchange Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    L. V. Titov and L. A. Gavrilova, Zh. Neorgan. Khim.,15, No. 11, 2899 (1970).Google Scholar
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    L. V. Titov, E. R. Eremin, L. A. Gavrilova, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 180 (1970).Google Scholar
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Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • L. V. Titov
    • 1
  • L. A. Gavrilova
    • 1
  • E. R. Eremin
    • 1
  • S. S. Mishchenchuk
    • 1
  • V. Ya. Rosolovskii
    • 1
  1. 1.Institute of New Chemical ProblemsAcademy of Sciences of the USSRUSSR

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