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Addition reactions of hypophosphorous acid derivatives to unsaturated compounds

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Conclusions

  1. 1.

    A study was made of the reactions of sodium hypophosphite and butyl hypophosphite with allyl alcohol, allyl acetate and allyl cyanide.

  2. 2.

    A method was developed for the preparation of the acid chlorides of theγ-acetoxypropyl- and γ-cyanopropylphosphonic acids, and also of the acid chloride of bis-(γ-acetoxypropyl)phosphinic acid.

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Literature cited

  1. 1.

    G. M. Vinokurova and I. A. Aleksandrova, Izv. Akad. Nauk SSSR, Ser. Khim., 884 (1969).

  2. 2.

    E. E. Nifant'ev and L. V. Matveeva, Zh. Obshch. Khim.,37, 1962 (1967).

  3. 3.

    B. E. Ivanov and L. A. Kudryavtseva, Izv. Akad. Nauk SSSR, Ser. Khim., 1498 (1967).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1315–1316, June, 1971.

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Aleksandrova, I.A., Ufimtseva, L.I. Addition reactions of hypophosphorous acid derivatives to unsaturated compounds. Russ Chem Bull 20, 1218–1219 (1971). https://doi.org/10.1007/BF00855385

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Keywords

  • Sodium
  • Alcohol
  • Acetate
  • Chloride
  • Cyanide