A correlation between the logarithms of the rate constants for the reaction of bromoquinoid compounds with morpholine and the Taft σ* constants, the logarithms of the rate constants, and the first half-wave potentials for the polarographic reduction of the bromoquinoid compounds was detected.
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A. A. Volod'kin, D. Kh. Rasuleva, V. V. Ershov, A. I. Prokov'ev, S. P. Solodovnikov, N. N. Bubnov, and S. G. Kukes, Izv. Akad. Nauk SSSR, Ser. Khim., 1212 (1972).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1446–1448, June, 1972.
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Rasuleva, D.K., Volod'kin, A.A., Ershov, V.V. et al. Effect of the nature of the substituents on the reactivities of bromoquinoid compounds in processes involving the transfer of one electron. Russ Chem Bull 21, 1403–1405 (1972). https://doi.org/10.1007/BF00854581
- Polarographic Reduction