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Synthesis and nitration of dimethyl-(3-thienyl)sulfonium salts

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Conclusions

A method was developed for the synthesis of the difficultly accessible methyl (5-nitro-3-thienyl) sulfide, which consisted in the conversion of methyl 3-thienyl sulfide to the sulfonium salt, with subsequent nitration and demethylation.

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Literature cited

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    Ya. L. Gol'dfarb, N. S. Ksenzhek, and L. I. Belen'kii, Khim. Geterotsikl. Soedin., 165 (1972).

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    L. I. Belen'kii, N. S. Ksenzhek, and Ya. L. Gol'dfarb, Khim. Geterotsikl. Soedin., 310 (1972).

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    R. J. Abraham and W. A. Thomas, J. Chem. Soc., 3739 (1964).

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    R.A. Hoffman and S. Gronowitz, Arkiv Kemi,16, 277 (1960).

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    S. Gronowitz, Arkiv Kemi,13, 276 (1958);16, 277 (1960).

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    S. Gronowitz and N. Gigos, Acta Chem. Scand.,16, 2823 (1967).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1161–1163, May, 1973.

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Gol'dfarb, Y.L., Ksenzhek, N.S. & Belen'kii, L.I. Synthesis and nitration of dimethyl-(3-thienyl)sulfonium salts. Russ Chem Bull 22, 1124–1125 (1973). https://doi.org/10.1007/BF00854269

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Keywords

  • Methyl
  • Sulfonium
  • Sulfide
  • Dimethyl
  • Nitration