Alkali metal perchloratoborates

  • V. P. Babaeva
  • V. Ya. Rosolovskii
Inorganic Chemistry

DOI: 10.1007/BF00854006

Cite this article as:
Babaeva, V.P. & Rosolovskii, V.Y. Russ Chem Bull (1973) 22: 476. doi:10.1007/BF00854006


  1. 1.

    Two methods have been developed for the production of perchloratoborates: the action of boron chloride on a solution of the metal chlorate in perchloric acid and the action of perchloric acid on metal chloridoborates. The use of a minimum excess of perchloric acid, containing 20–30% Cl2O7, ensures high purity of the products obtained.

  2. 2.

    Cesium, rubidium, and potassium perchloratoborates were isolated and investigated. The IR spectra of the perchloratoborates indicate a closeness of the structure of the B-OClO3 group to the structure of ROClO3 in the molecules of HOClO3, ClO3OClO3, ClOClO3, and BrOClO3.


Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • V. P. Babaeva
    • 1
  • V. Ya. Rosolovskii
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of Sciences of the USSRUSSR

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