Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

IR spectra of organolead acetylenic compounds

  • 21 Accesses

Conclusions

  1. 1.

    The IR spectra of organolead compounds with the general formula R3PbC≡CR′ were obtained where R =CH3, C2H5; R′=H, CH=CH2, CH2Cl, Si(CH3)3, Sn(C2H5)3, Pb(C2H5)3, as well as the reaction products of trialkylplumbane with acetylenicα-oxygen-containing compounds.

  2. 2.

    The decrease in the vibration frequency of the acetylenic bond in lead-containing compounds is due primarily to an increase in the “metallic character” of the properties of lead.

  3. 3.

    The presence of lead does not lead to any significant changes in the vibrations of the remaining groups and atoms.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    M. F. Shostakovskii, N. I. Shergina, N. V. Komarov, and Yu. V. Maroshin, Izv. Akad. Nauk SSSR, Ser. Khim., 1606 (1964).

  2. 2.

    M. F. Shostakovskii, N. I. Shergina, N. V. Komarov, E. I. Brodskaya, and I. I. Igonina, Izv. Akad. Nauk SSSR, Ser. Khim., 1126 (1964).

  3. 3.

    N. I. Shergina, N. I. Golovanova, R. G. Mirskov, and V. M. Vlasov, Izv. Akad. Nauk SSSR, Ser. Khim., 1378 (1967).

  4. 4.

    M. F. Shostakovskii, N. I. Shergina, N. I. Golovanova, N. V. Komarov, and V. K. Misyunas, Zh. Obshch. Khim.,35, 1768 (1965).

  5. 5.

    M. F. Shostakovskii, N. I. Shergina, E. I. Brodskaya, O. G. Yarosh, and N. V. Komarov, Dokl. Akad. Nauk SSSR,158, 1143 (1964).

  6. 6.

    J. C. Masson and P. Cadiot, Bull. Soc. Chim. France, 3518 (1965).

  7. 7.

    V. S. Zavgorodnii and A. A. Petrov, Dokl. Akad. Nauk SSSR,143, 855 (1962).

  8. 8.

    R. West and R. H. Baney, J. Phys. Chem.,64, 822 (1960).

  9. 9.

    M. F. Shostakovskii, N. V. Komarov, T. I. Ermolova, and G. R. Langvagen, Izv. Akad. Nauk SSSR, Ser. Khim., 2604 (1968).

  10. 10.

    N. N. Vyshinskii, Yu. A. Aleksandrov, and N. K. Rudnevskii, Izv. AN SSSR, Ser. Fiz., 1265 (1962).

  11. 11.

    M. F. Shostakovskii, N. V. Komarov, and T. I. Ermolova, Dokl. Akad. Nauk SSSR,175, 1079 (1967).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1565–1569, July, 1970.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Shostakovskii, M.F., Shergina, N.I., Ermolova, T.I. et al. IR spectra of organolead acetylenic compounds. Russ Chem Bull 19, 1475–1478 (1970). https://doi.org/10.1007/BF00853838

Download citation

Keywords

  • General Formula
  • Vibration Frequency
  • Metallic Character
  • Acetylenic Compound
  • Acetylenic Bond