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Exchange reactions of bis(triethylgermyl)mercury with organotin halides and related compounds

  • O. A. Kruglaya
  • B. I. Petrov
  • G. N. Bortnikov
  • N. S. Vyazankin
Organic and Biological Chemistry
  • 19 Downloads

Conclusions

  1. 1.

    bis(Triethylgermyl)mercury and compounds of the (C2H5)3SnX series, where X=Cl, NCO, OCOCH3, OCH3, N(C2H5)2, CH2COOCH3, enter into the reaction of exchanging the X substituents by (C2H5)3Ge radicals, with the formation of triethylstannyltriethylgermane, mercury and (C2H5)3GeX. The reaction proceeds with the intermediate formation of derivatives containing the Ge-Hg-X group.

     
  2. 2.

    The exchange reactions of diethyldichlorostannane and diethyldimethoxystannane with bis(triethylgermyl) mercury proceed by an analogous scheme.

     

Keywords

Mercury Exchange Reaction Halide Related Compound Intermediate Formation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • O. A. Kruglaya
    • 1
  • B. I. Petrov
    • 1
  • G. N. Bortnikov
    • 1
  • N. S. Vyazankin
    • 1
  1. 1.Institute of ChemistryAcademy of Sciences of the USSRUSSR

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