The IR absorption spectra of hydrated, anhydrous (as well as deuterated acids) nitrilotriacetates of Cu2+ and Ni2+ of various compositions were investigated.
Some conclusions were drawn on the structures of the compounds studied (on the dentateness of nitrilotriacetic acid, the nature of the M-N and M-Ocarb bonds, and the role of water of hydration).
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J. V. Dusky and M. Spitzmann, J. Pract. Chem.,96, 112 (1917).
H. Britzinger and G. Hesse, Z. Anorgan. Chem.,249, 299 (1942).
P. Pfeiffer and W. Offermann, Ber.,75, 1 (1942).
N. D. Mitrofanova, L. I. Martynenko, and Vikt. I. Spitsyn, Izv. Akad. Nauk SSSR, Ser. Khim., 2115 (1971).
W. Kelmm and K. H. Raddatz, Z. Anorgan. Chem.,250, 240 (1942).
J. Tomita and K. Ueno, Bull. Chem. Soc., Japan,36, 1069 (1963).
N. D. Mitrofanova, L. I. Martynenko, and A. I. Grigor'ev, Zh. Neorgan. Khimii,9, 320 (1964).
A. I. Grigor'ev, N. D. Mitrofanova, and L. I. Martynenko, Zh. Neorgan. Khimii,10, 320 (1965).
G. S. Smitz and J. H. Hoard, J. Amer. Chem. Soc.,81, 556 (1959).
N. P. Potanova and L. I. Martynenko, Zh. Neorgan. Khimii,12, 192 (1968).
L. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963).
V. M. Vdovenko (editor), Spectroscopic Methods in the Chemistry of Complex Compounds [in Russian], Khimiya (1964).
A. Novak, M. Cotreit, and J. Jossef-Dubuen, Bull. Soc. Chim. France, 2536 (1965).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], Mir (1966).
A. Novak, M. Cotreit, J. Joussef-Dubuen, and J. Lascombe, Inorgan. Chem.,4, 767 (1965).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2122–2128, October, 1971.
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Mitrofanova, N.D., Martynenko, L.I. & Spitsyn, V.I. IR spectroscopic study of the structure of solid copper and nickel nitrilotriacetates. Russ Chem Bull 20, 2010–2014 (1971). https://doi.org/10.1007/BF00851239
- Absorption Spectrum
- Spectroscopic Study