Acidity of niccolocene in dimethyl sulfoxide and methanol solutions

  • E. V. Bykova
  • V. N. Setkina
  • D. N. Kursanov
Brief Communications

Conclusions

The acidity of niccolocene in dimethyl sulfoxide-methanol solution during potassium methoxide catalysis was determined by measuring the isotopic hydrogen-exchange rate constants of 9-phenylxanthene and niccolocene in this mixture of solvents.

Keywords

Methanol Potassium Catalysis Acidity Dimethyl 
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Literature cited

  1. 1.
    D. N. Kursanov, E. V. Bykova, and V. N. Setkina, Dokl. Akad. Nauk SSSR,184, 100 (1969).Google Scholar
  2. 2.
    E. V. Bykova and V. N. Setkina, Izv. Akad. Nauk SSSR, Ser. Khim., 1628 (1967).Google Scholar
  3. 3.
    W. D. Kollmeyer and D. J. Cram, J. Amer. Chem. Soc.,90, 1784 (1968).Google Scholar
  4. 4.
    F. S. Yakushin, A. I. Shatenshtein, V. N. Setkina, and D. N. Kursanov, Summaries of Papers Presented at the Fifth International Congress on Organometallic Chemistry in Moscow [in Russian], Vol. 1, No. 162, VINITI (1971), p. 419.Google Scholar
  5. 5.
    J. F. Cordes, Ber.,95, 3084 (1962).Google Scholar
  6. 6.
    M. Gomberg and D. Nishida, J. Amer. Chem. Soc.,45, 191 (1923).Google Scholar
  7. 7.
    F. W. Hobden, E. F. Jonston, L. H. P. Weldon, and C. L. Wilson, J. Chem. Soc., 61 (1939); A. Murray and D. L. Williams, Syntheses of Organic Compounds with Hydrogen Isotopes [Russian translation], IL (1961), p. 138.Google Scholar
  8. 8.
    A. I. Shatenshtein, E. A. Yakovleva, E. N. Zvyagintseva, Ya. M. Varshavskii, E. A. Izrailevich, and N. M. Dykhno, Isotopic Analysis of Water [in Russian], Izd. AN SSSR (1957), p. 167.Google Scholar

Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • E. V. Bykova
    • 1
  • V. N. Setkina
    • 1
  • D. N. Kursanov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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