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Investigation of the hydrogenation of acetophenone by a kinetic isotopic method

  • G. V. Isagulyants
  • N. V. Borunova
  • L. Kh. Freidlin
  • S. S. Danielova
  • L. I. Kovalenko
Physical Chemistry
  • 21 Downloads

Conclusions

  1. 1.

    The stepwise mechanism of the reduction of acetophenone in the presence of Rh and Co catalysts was investigated by the kinetic isotopic method.

     
  2. 2.

    In the presence of a Rh catalyst, methylcyclohexylcarbinol is formed primarily through the stage of methylphenylcarbinol, and ethylbenzene through the stage of methylphenylcarbinol, as well as directly from acetophenone.

     
  3. 3.

    In the presence of a skeletal Co catalyst, ethylbenzene is produced primarily through the stage of methylphenylcarbinol.

     

Keywords

Hydrogenation Acetophenone Ethylbenzene Isotopic Method Stepwise Mechanism 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    Yu. I. Derbentsev, G. V. Isagulyants, L. F. Rar, D. L. Pakul', and A. A. Balandin, Dokl. Akad. Nauk SSSR,177, 1371 (1967).Google Scholar
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Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • G. V. Isagulyants
    • 1
  • N. V. Borunova
    • 1
  • L. Kh. Freidlin
    • 1
  • S. S. Danielova
    • 1
  • L. I. Kovalenko
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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