The condensation of cis-1-vinyl-8-methyl-Δ1-hexahydroindene-5-one (I) with citraconic anhydride, quinone, methyl acrylate, nitropropylene, and the methyl ester of trans-ß-nitroacrylic acid was studied.
The lactoacid (IX), containing structural elements modeling the A ring of the gibberellins was produced.
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V. F. Kucherov, I. A. Gurvich, and B. A. Rudenko, Izv. AN SSSR. Ser. Khim.,1964, 1456.
V. F. Kucherov, I. M. Mil'shtein, and I. A. Gurvich, Zh. Obshch. Khimii,31, 2832 (1961).
V. F. Kucherov and I. A. Gurvich, Izv. AN SSSR. Otd. Khim. n.,1962, 3637
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8 pp. 1507–1509, August, 1964
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Gurvich, I.A., Kucherov, V.F. Cis-1-vinyl-8-methyl-δ1-hexahydroindene-5-one in reactions of diene synthesis. Russ Chem Bull 13, 1409–1411 (1964). https://doi.org/10.1007/BF00850345
- Methyl Ester