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Steric hindrances in certain bi- and tricyclic systems

Conclusions

  1. 1.

    The conformations and energies of stress of 11 bicyclic and four tricyclic systems were calculated by minimization of the potential functions.

  2. 2.

    Of the five calculated structures for which there are data on the geometry (with the exception of bicyclo- [1,1,0]-butane, the geometry found for which is somewhat doubtful), quite satisfactory agreement with the experiment was obtained. For the remaining molecules, our data can be considered as a prediction.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1963–1971, September, 1970.

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Zaripov, N.M., Dashevskii, V.G. & Naumov, V.A. Steric hindrances in certain bi- and tricyclic systems. Russ Chem Bull 19, 1848–1854 (1970). https://doi.org/10.1007/BF00849758

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Keywords

  • Potential Function
  • Tricyclic
  • Butane
  • Steric Hindrance
  • Satisfactory Agreement