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Spectrophotometric investigation of donor-acceptor complexes of polyvinylcarbazole

Conclusions

  1. 1.

    Polyvinylcarbazole, carbazole, and vinylcarbazole in chloroform solutions form complexes with charge transfer with monomer electron acceptors with a 1∶1 composition.

  2. 2.

    The stability constants of the complexes at room temperature were calculated according to the Benesi-Hildebrand method.

  3. 3.

    The ionization potentials of polyvinylcarbazole, vinylcarbazole, and carbazole were calculated according to the Briegleb-Czekalle equation.

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Literature cited

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 57–61, Jaunary, 1971.

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Levina, F.A., Sidaravichyus, I., Peredereeva, S.I. et al. Spectrophotometric investigation of donor-acceptor complexes of polyvinylcarbazole. Russ Chem Bull 20, 49–52 (1971). https://doi.org/10.1007/BF00849317

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Keywords

  • Chloroform
  • Charge Transfer
  • Electron Acceptor
  • Stability Constant
  • Ionization Potential