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Reactions of bis(triethylgermyl)cadmium

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Conclusions

  1. 1.

    Bis(triethylgermyl)cadmium reacts with bromobenzene only under the influence of ultraviolet light, with the formation of triethylbromogermane, triethylphenylgermane, diphenylcadmium and cadmium bromide.

  2. 2.

    The reaction of bis(triethylgermyl)cadium with CCl4 yields triethylchlorogermane, CdCl2 and bis(triethylgermyl)dichloromethane.

  3. 3.

    Bis(triethylgermyl)cadmium and bis (triethylgermyl)mercury react with Li or Na in tetrahydrofuran with the formation of the triethylgermyl derivative of lithium or sodium.

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Literature cited

  1. 1.

    N. S. Vyazankin, G. A. Razuvaev, and E. N. Gladyshev, Dokl. AN SSSR,155, 830 (1964).

  2. 2.

    C. A. Kraus and E. A. Flood, J. Amer. Chem. Soc.,54, 1635 (1932).

  3. 3.

    F. B. Smith and C. A. Kraus, J. Amer. Chem. Soc.,74, 5398 (1950).

  4. 4.

    C. A. Kraus and S. N. Glarum, J. Amer. Chem. Soc.,72, 5398 (1950).

  5. 5.

    Organometallic Chemistry [Russian translation], Editor-in-Chief H. Zeiss, Izd. “Mir,” Moscow (1964).

  6. 6.

    R. J. Cross and F. Glockling, J. Chem. Soc.,1964, 4125.

  7. 7.

    N. S. Vyazankin, G. A. Razuvaev, and V. T. Bychkov, Dokl. AN SSSR,158, 382 (1964).

  8. 8.

    N. S. Vyazankin, G. A. Razuvaev, and V. T., Bychkov, Zh. obshch. khim.,35, 395 (1965).

  9. 9.

    H. Gilman and D. Aoki, J. Organometallic Chem.,1, 449 (1964).

  10. 10.

    H. H. Anderson, J. Amer. Chem. Soc.,79, 326 (1957).

  11. 11.

    C. Eaborn and K. Pande, J. Chem. Soc.,1960, 3202.

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Vyazankin, N.S., Razuvaev, G.A., Bychkov, V.T. et al. Reactions of bis(triethylgermyl)cadmium. Russ Chem Bull 15, 533–534 (1966). https://doi.org/10.1007/BF00846124

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Keywords

  • Sodium
  • Mercury
  • Lithium
  • Cadmium
  • Bromide