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On the anomalous behavior of thiodiglycol under conditions of the vinylation reaction

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Conclusions

The interaction of thiodiglycol with acetylene under the usual vinylation conditions is accompanied by an anomalous reaction, leading to vinyl ethers of monothioethylene glycol.

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Literature cited

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Shostakovskii, M.F., Atavin, A.S., Amosova, S.V. et al. On the anomalous behavior of thiodiglycol under conditions of the vinylation reaction. Russ Chem Bull 15, 522–524 (1966). https://doi.org/10.1007/BF00846120

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Keywords

  • Ether
  • Glycol
  • Vinyl
  • Acetylene
  • Anomalous Behavior