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Ammonolysis of alkyl- and aryl-trichlorosilanes

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Conclusions

  1. 1.

    As a result of the ammonolysis of alkyltrichlorosilanes with gaseous ammonia in a solvent low-molecular-weight crystalline products of general formula [RSi(NH)1.5]6 were obtained together with soluble low-melting polymers of cyclic structure.

  2. 2.

    The ammonolysis of trichlorophenylsilane leads to the formation of a soluble infusible polymer.

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Literature cited

  1. 1.

    K. Hozawa and E. Nojimoto, Kogyo Kagaku Zasshi59, 1445 (1956); Chem. Abstrs.53, 4176 (1959).

  2. 2.

    N. D. Cheronis and E. L. Gustus, U. S. Pat. 2579416, 1951, Chem. Abstrs.46, 2850 (1952).

  3. 3.

    E. Larsson, Acta Chem. Scand.8, 1084 (1954).

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Andrianov, K.A., Kotrelev, G.V. Ammonolysis of alkyl- and aryl-trichlorosilanes. Russ Chem Bull 15, 443–445 (1966). https://doi.org/10.1007/BF00846101

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Keywords

  • Polymer
  • Ammonia
  • General Formula
  • Cyclic Structure
  • Gaseous Ammonia