As a result of the ammonolysis of alkyltrichlorosilanes with gaseous ammonia in a solvent low-molecular-weight crystalline products of general formula [RSi(NH)1.5]6 were obtained together with soluble low-melting polymers of cyclic structure.
The ammonolysis of trichlorophenylsilane leads to the formation of a soluble infusible polymer.
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K. Hozawa and E. Nojimoto, Kogyo Kagaku Zasshi59, 1445 (1956); Chem. Abstrs.53, 4176 (1959).
N. D. Cheronis and E. L. Gustus, U. S. Pat. 2579416, 1951, Chem. Abstrs.46, 2850 (1952).
E. Larsson, Acta Chem. Scand.8, 1084 (1954).
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Andrianov, K.A., Kotrelev, G.V. Ammonolysis of alkyl- and aryl-trichlorosilanes. Russ Chem Bull 15, 443–445 (1966). https://doi.org/10.1007/BF00846101
- General Formula
- Cyclic Structure
- Gaseous Ammonia