A study was made of the reactions of phenyl 2,2,2-trichloro-1,1-dimethylethyl phosphorochloridite with alcohols with formation of phosphorous esters containing three different alkoxyls. The acid chloride does not react with 2,6-xylenol, probably because of the presence of steric hindrance.
The rearrangement of the alkyl phenyl 2,2,2-trichloro-1,1-dimethylethyl phosphities with methyl iodide goes with elimination of the unsubstituted aliphatic group.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2010–2013, November 1965
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Khairullin, V.K., Sobchuk, T.I. Preparation and rearrangement of alkyl phenyl 2,2,2-trichloro-1,1-dimethylethyl phosphites. Russ Chem Bull 14, 1974–1977 (1965). https://doi.org/10.1007/BF00845893