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Polarographic reduction of allyl complexes of palladium

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Conclusions

  1. 1.

    The polarographic behavior of allyl complexes of palladium C3H5PdX(X=Cl, Br, I, C5H5) was studied in anhydrous and aqueous alcohol media.

  2. 2.

    A possible mechanism of the electrochemical reduction was proposed.

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Literature cited

  1. 1.

    S. P. Gubin, A. Z. Rubezhov, B. L. Vinch and A. N. Nesmeyanov, Tetrahedron Letters,1964, 2881.

  2. 2.

    H. D. Murdoch and E. A. C. Lucken, Helv. Chim. acta,47, No. 6, 1517 (1964).

  3. 3.

    A. A. Vlcek, in Progress in Inorganic Chemistry, Interscience, New York-London, 1963,5, p. 362.

  4. 4.

    A. Kirrmann and M. Kleine Peter, Bull. Soc. chim., France,1957, 894.

  5. 5.

    V. Vojir, Coll. Czech. Chem. Comm.,16, 488 (1951).

  6. 6.

    H. Christ and D. R. Hüttel, Angew. Chemie,75, 921 (1963).

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Gubin, S.P., Denisovich, L.I. Polarographic reduction of allyl complexes of palladium. Russ Chem Bull 15, 125–127 (1966). https://doi.org/10.1007/BF00845852

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Keywords

  • Alcohol
  • Palladium
  • Allyl
  • Electrochemical Reduction
  • Aqueous Alcohol