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Polarographic reduction of allyl complexes of palladium

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  1. 1.

    The polarographic behavior of allyl complexes of palladium C3H5PdX(X=Cl, Br, I, C5H5) was studied in anhydrous and aqueous alcohol media.

  2. 2.

    A possible mechanism of the electrochemical reduction was proposed.

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Literature cited

  1. 1.

    S. P. Gubin, A. Z. Rubezhov, B. L. Vinch and A. N. Nesmeyanov, Tetrahedron Letters,1964, 2881.

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    H. D. Murdoch and E. A. C. Lucken, Helv. Chim. acta,47, No. 6, 1517 (1964).

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    A. A. Vlcek, in Progress in Inorganic Chemistry, Interscience, New York-London, 1963,5, p. 362.

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    A. Kirrmann and M. Kleine Peter, Bull. Soc. chim., France,1957, 894.

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    V. Vojir, Coll. Czech. Chem. Comm.,16, 488 (1951).

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    H. Christ and D. R. Hüttel, Angew. Chemie,75, 921 (1963).

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Gubin, S.P., Denisovich, L.I. Polarographic reduction of allyl complexes of palladium. Russ Chem Bull 15, 125–127 (1966). https://doi.org/10.1007/BF00845852

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  • Alcohol
  • Palladium
  • Allyl
  • Electrochemical Reduction
  • Aqueous Alcohol