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New data on the free radical reaction of alcohols with olefins

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The radical reaction of alcohols with alkenes-1 proceeds at both carbon atoms of the double bond. As a result, a mixture of the two 1 ∶ 1 adducts, consisting chiefly of the addition products of the alcohol at the CH2 group, with a small content (4–13%) of the addition product at the CH group, is formed.

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Vorob'ev, V.D., Nikishin, G.I. New data on the free radical reaction of alcohols with olefins. Russ Chem Bull 15, 112–113 (1966). https://doi.org/10.1007/BF00845847

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  • Alcohol
  • Adduct
  • Carbon Atom
  • Double Bond
  • Radical Reaction