Summary
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1.
In a study of the thermal decomposition of sodium ozonide, on a Mc Bain balance at the temperatures −20, −10, 0, and 10°, curves of the conversion of sodium ozonide and the rate of its decomposition were obtained.
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2.
The process of thermal decomposition of sodium ozonide to NaO2 occurs at −20 and −10°.
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3.
At temperatures above 0°, the process of thermal decomposition of sodium ozonide is accompanied by the process of interaction of the NaO2 formed with H2O, and decomposition proceeds to the formation of NaOH.
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Literature cited
W. Stecher and H. Thienemann, Ber. 2096 (1920).
G. P. Nikol'skii, Z. A. Bagdasar,Yan, and I. A. Kazaranovskii, Dokl. AN SSSR77, 69 (1951).
S. A. Tokareva and M. S. Dobrolyubova, Izv. AN SSSR, Ser. Khim.1964, No. 4
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Tokareva, S.A., Pilipenko, G.P. Thermal decomposition of sodium ozonide. Russ Chem Bull 13, 686–688 (1964). https://doi.org/10.1007/BF00845322
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DOI: https://doi.org/10.1007/BF00845322