Summary
The electronic absorption spectra of someSchiff bases derived from 3-amino-1,2,4-triazole have been investigated in organic solvents of different polarities. Assignment of the absorption bands, solvent effects, and spectral structure correlations are considered. The fundamental IR bands and the main signals in the1H NMR spectra are assigned and discussed with respect to the effect of substituents on the phenyl ring. A change of the electrical conductance of the compounds with increasing temperature is observed for the solid samples.
Zusammenfassung
Die UV/Vis-Spektren einiger von 3-Amino-1,2,4-triazol abgeleiteterSchiffscher Basen wurden in Lösungsmitteln unterschiedlicher Polarität bezüglich Zuordnung der Banden, Lösungsmitteleffekten und Spektrum-Struktur — Korrelationen untersucht. Die wesentlichen IR- und1H-NMR — Signale wurden zugeordnet und werden mit Substituenteneffekten in Beziehung gesetzt. Im Festzustand zeigen die Proben eine Änderung der elektrischen Leitfähigkeit mit steigender Temperatur.
Similar content being viewed by others
References
Krasoviskii B. M., Bolotin B. M., Nurmukhametor R. N. (1964) Zh. Obshch. Khim.34: 3786
Dudek G. O., Dudek F. P. (1966) J. Am. Chem. Soc.88: 2407
Cohen M. D., Flavian S. (1967) J. Chem. Soc. (B)312: 317
El-Bayoumi M. A. (1971) J. Am. Chem. Soc.93: 586
Issa R. M., El-Samahy A. A., Etaiw S. H. (1974) Z. Phys. Chem. Leipzig255: 853
Kovacic J. E. (1967) Spectrochim Acta23A: 183
Mahmoud M. R., El-Haty M. T. (1980) Inorg. Nucl. Chem.42: 349
Issai R. M., Aly F. A., Gaber M., Ayad M. I. (1990) Communications de la Faculte des Science de l'Universite d'Ankara
Williams J. O. (1978) Advances in Physical Organic Chemistry, vol. 16. (Gold V., Bethell D., eds). Academic Press, London New York
Szeut-Gyorgyi A. (1941) Science93: 609
Abou Sekkaina M. M., Issa Y. M. (1985) Thermochim. Acta83: 321
Vogel A. I. (1975) A Textbook of Practical Organic Chemistry Including Qualitative Organic Analysis, 3rd ed. Longman, London
Gaber M., Dessouki H. A., Issa Y. M. (1986) Kolorisztikai Ertesito1: 2
Khattab M. A., El-Baradie H. Y. F., Issa R. M., Maghrabi J. Y. (1979) Ind. J. Chem.18(1A): 144
Gati L., Szalay L. (1969) Acta Phys. Chim.5: 87
Suppan P. (1968) Chem. Soc. (A): 3125
Reichardt C. (1973) Lösungsmittel Effekte in der organischen Chemie. Verlag Chemie, Weinheim
Kosower E. M. (1968) An Introduction to Physical Organic Chemistry. Wiley, New York, p. 301
Blythe A. R. (1979) Electrical properties of polymers. Cambridge, London New York, p. 107
Issa Y. M., Hindawey A. M., Marghalani Y. A., Issa R. M. (1979) Proceedings of the Pakistan Academy of Sciences16: 1
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ayad, M.M., Mansour, I.A. Spectroscopic and conductometric studies on someSchiff bases. Monatsh Chem 126, 385–392 (1995). https://doi.org/10.1007/BF00813200
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00813200