Kinetik und Mechanismus des Ligandentausches zwischen Thallium(III)oxinat und Eisen(III) in Propylencarbonat
Anorganische Und Physikalische Chemie
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Kinetics and mechanism of the oxinate transfer from thallium(III)oxinate to iron(III) in propylenecarbonate
Abstract
The transfer of oxinate ions from thallium (III)oxinate to trivalent Fe(DMF) 6 3+ in propylenecarbonate takes place via rearrangements within a rapidly formed binuclear thallium(III)—iron(III) complex. In a last rapid step this rearranged complex reacts with excess reactants to the final products whose composition accordingly depends on the ratio of the reactant concentrations.
Keywords
Kinetics Ligand-transfer Thallium (III)Preview
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