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Synthesis and characterization of Co(II), Ni(II), and Cu(II) complexes of salicylal-4-aminoantipyrine and 2-hydroxy-1-naphthol-4-aminoantipyrine and their adducts

Synthese und Charakterisierung von Co(II), Ni(II) und Cu(II)-Komplexen von Salicylal-4-aminoantipyrinen und 2-Hydroxy-1-naphthol-4-aminoantipyrinen und ihren Addukten

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

The electrochemical oxidation of anodic Co, Ni and Cu in acetone solutions of 4-aminoantipyrine Schiff base of salicyaldehyde (SAAP) and 2-hydroxy-1-naphthaldehyde (NAAP) [=R(OH)] gave the title complexes in high yields. When neutral mono- or bidentate donors were present in the solution, the products were the 1:1 adducts of mixed complexes. The complexes were characterized by elemental analysis, IR, electronic, and ESR spectra as well as magnetic moment measurements. The thermal (DTA) behaviour and electrical properties of some complexes were investigated in the solid state and correlated with the structure of the complexes.

Zusammenfassung

Die elektrochemische Oxidation von Co, Ni und Cu in Lösungen von 4-Aminoantipyrin-Schiff-Basen von Salicylaldehyd (SAAP) und 2-Hydroxy-1-naphthaldehyd (NAAP) ergab die im Titel genannten Komplexe in hohen Ausbeuten. Bei Anwesenheit neutraler mono- oder bidentater Donoren in Lösung entstehen 1:1-Addukte der gemischten Komplexe. Die Komplexe wurden mittels Elementaranalyse, IR, Elektronen- und ESR-Spektren, sowie mittels Messungen der magnetischen Momente charakterisiert. Von einigen Komplexen wurden thermisches Verhalten (DTA) und die elektrischen Eigenschaften untersucht und mit der Struktur der Komplexe korreliert.

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References

  1. Janik B., Sawicki S. (1970) Mikro. Chim. Acta: 1050

  2. Craciunescu D. G. (1977) An. R. Acad. Farm.43: 265

    Google Scholar 

  3. Hosler J., Tschanz C., Hignite C. E., Azarnoff D. L. (1986) J. Invest. Dermatol.74: 51

    Google Scholar 

  4. Morishige K. (1980) Anal. Chim. Acta121: 301

    Google Scholar 

  5. Shankar G., Premkumar R. R., Ramalingam S. K. (1986) Polyhedron5: 991

    Google Scholar 

  6. Donia A. M., EL-Saied F. A. (1988) Polyhedron7: 2149

    Google Scholar 

  7. Radhakrishnan P. K. (1986) Polyhedron5: 995

    Google Scholar 

  8. Kuncheria B., Indrasenan P. (1988) Polyhedron7: 143

    Google Scholar 

  9. Radhakrishnan T., Joseph P. T., Prabkaran C. P. (1976) J. Inorg. Nucl. Chem.38: 2217

    Google Scholar 

  10. Johnson D. K., Stoklosa H. J. Wasson J. R., Seebach G. L. (1975) J. Inorg. Nucl. Chem.37: 1397

    Google Scholar 

  11. Mabrouk H. E., Tuck D. G. (1988) Inorg. Chim. Acta145: 237

    Google Scholar 

  12. Mabrouk H. E., Tuck D. G., Khan M. A. (1987) Inorg. Chim. Acta129: 75

    Google Scholar 

  13. Mabrouk H. E., Tuck D. G. (1988) J. Chem. Soc. Dalton Trans. 2539

  14. Geloso C., Mabrouk H. E., Tuck D. G. (1989) J. Chem. Soc. Dalton Trans. 1759

  15. Mabrouk H. E., Tuck D. G. (1989) Can. J. Chem.67: 746

    Google Scholar 

  16. Chadha R. K., Kumar R., Tuck D. G. (1988) Polyhedron7: 1121

    Google Scholar 

  17. Khan M. A., Kumar R., Tuck D. G. (1988) Polyhedron7: 49

    Google Scholar 

  18. Black S. J., Einstien F. W. B., Hayes P. C., Kumar R., Tuck D. G. (1986) Inorg. Chem.25: 4181

    Google Scholar 

  19. Green J. H., Kumar R., Seudeal N., Tuck D. G. (1989) Inorg. Chem.28: 123

    Google Scholar 

  20. Annan T. A., Peppe C., Tuck D. G. (1990) Can. J. Chem.68: 432

    Google Scholar 

  21. Bastida R., Bermejo M. R., Louro M. S., Romero J., Sousa A., Fenton D. E. (1988) Inorg. Chim. Acta145: 167

    Google Scholar 

  22. Banait J. S., Pahil P. K. (1965) Polyhedron5: 1865

    Google Scholar 

  23. Mabrouk H. E., AL-Asmy A. A., Mounir M. (1991) Trans. Metal Chem., in press

  24. Mabrouk H. E., AL-Asmy A. A., AL-Ansi T. Y., Mounir M. (1991) Bull. Soc. Chim. France128: 309

    Google Scholar 

  25. Gaber M., Mabrouk H. E., EL-Sonbati A. Z., EL-Hefnawy G. B. (1991) Trans. Metal Chem., in press

  26. Amer S. A., Gaber M., Issa R. M. (1988) Polyhedron7: 2635

    Google Scholar 

  27. Issa R. M., et al. (1981) J. Inorg. Nucl. Chem.43: 303; (1980) Ann. Chim. (Rome)70: 33

    Google Scholar 

  28. Nakamoto K. (1971) Infrared and Raman Spectra of Inorganic and Coordination Compounds. Wiley Interscience, New York

    Google Scholar 

  29. Wendlandt W. W. (1963) J. Inorg. Nucl. Chem.25: 833

    Google Scholar 

  30. Thomas J., Clarke T. A. (1968) J. Chem. Soc.A 1968: 457

    Google Scholar 

  31. Gaber M., Mabrouk H. E., Mounir M. (1991) Thermochimica Acta186: 89

    Google Scholar 

  32. Lever A. B. B. (1968) Inorganic Electronic Spectroscopy, Elsevier Amsterdam

    Google Scholar 

  33. Wallwork S. C., Addison W. E. (1965) J. Chem. Soc. 2925

  34. Patel B. V., Thaker B. T. (1986) Synth. React. Inorg. Met-Org. Chem.16: 1319

    Google Scholar 

  35. Mukkanti K., Pandeyea K. B., Singh R. P. (1982) Indian J. Chem.21 A: 641

    Google Scholar 

  36. Hathaway B. J., Tomlinson A. A. (1970) Coord. Chem. Rev.5: 1

    Google Scholar 

  37. Procter I. M., Hathaway B. J., Nicholls P. (1968) J. Chem. Soc.A 1968: 1678

    Google Scholar 

  38. Ballhausen C. J. (1962) Introduction to Ligand Field Theory. McGraw Hill, New York, p. 134

    Google Scholar 

  39. Hathaway B. J., Billing D. E. (1970) Coord. Chem. Rev.5: 143

    Google Scholar 

  40. Hathaway B. J., Dudley R. J., Nicholls P. (1968) J. Chem. Soc.A 1968: 1845

    Google Scholar 

  41. Dudley R. J., Hathaway B. J. (1970) J. Chem. Soc.A 1970: 1725

    Google Scholar 

  42. Fidone I., Stevens K. W. H. (1959) Proc. Phys. Soc. London73: 116

    Google Scholar 

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Author notes

  1. Mohamed M. Ayad

    Present address: Department of Science, T. T. Junior College, Al-Baha, Kingdom of Saudia Arabia

Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Sana'a University, Sana'a P.O. Box 11503, Yemen

    Mohamed Gaber, Hassan E. Mabrouk & Abd alla A. Ba-Issa

  2. Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt

    Mohamed M. Ayad

Authors
  1. Mohamed Gaber
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  2. Hassan E. Mabrouk
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  3. Abd alla A. Ba-Issa
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Gaber, M., Mabrouk, H.E., Ba-Issa, A.a.A. et al. Synthesis and characterization of Co(II), Ni(II), and Cu(II) complexes of salicylal-4-aminoantipyrine and 2-hydroxy-1-naphthol-4-aminoantipyrine and their adducts. Monatsh Chem 123, 1089–1097 (1992). https://doi.org/10.1007/BF00808271

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  • DOI: https://doi.org/10.1007/BF00808271

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