Monatshefte für Chemie / Chemical Monthly

, Volume 127, Issue 1, pp 43–49 | Cite as

Bemerkenswerte Wirt-Gast-Beziehungen in Tetraphenylphosphoniumsalzen vontris-Trithiocarbonato-Komplexen des As(III), Bi(III) und Fe(III)

  • A. Müller
  • E. Diemann
  • E. Krickemeyer
  • H. Bögge
  • C. Menke
  • C. Kuhlmann
Anorganische Und Physikalische Chemie
  • 26 Downloads

Remarkable host-guest relationships in tetraphenylphosphonium salts oftris-trithiocarbonato complexes of As(III), Bi(III), and Fe(III)

Summary

The structure and packing of the lattice of the compounds (PPh4)3[As(CS3)3] (1), (PPh4)3[Bi(CS3)3] (2), and (PPh4)3[Fe(CS3)3]·H2O (3) is discussed in terms of hostguest chemistry in a “soft” matrix of large cations. The hitherto unknown Fe-complex was characterized by elemental analysis and single crystal structure analysis. Here CS32− acts as a classical bidentate ligand, whereas in the case of the arsenic and bismut complexes, the coordination of this ligand is essentially unidentate due to an interaction with the lone pair on the central atom. For the last two complexes, there seems to be an influence of the packing on the coordination geometry.

Keywords

Trithiocarbonato complexes Tetraphenylphosphonium salts Host-guest chemistry 

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Copyright information

© Springer-Verlag 1996

Authors and Affiliations

  • A. Müller
    • 1
  • E. Diemann
    • 1
  • E. Krickemeyer
    • 1
  • H. Bögge
    • 1
  • C. Menke
    • 1
  • C. Kuhlmann
    • 1
  1. 1.Fakultät für Chemie der UniversitätLehrstuhl für Anorganische Chemie IBielefeldGermany

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