Monatshefte für Chemie / Chemical Monthly

, Volume 114, Issue 11, pp 1259–1265 | Cite as

Bromination of resin acid derivatives

  • Ernst Haslinger
  • Hermann Kalchhauser
  • Harald Steindl
Organische Chemie Und Biochemie
Received:
Accepted:

Abstract

Radicalic bromination of1,2, and3 leads to products with halogen in the isopropyl group. The corresponding olefins are obtained by elimination of HBr.

Keywords

17,19-Dinoratis-15-ene-4,13,14-tricarboxylic acid, 16-(1-methylethyl), cyclic-13,14-anhydride (4α,8α,12α) and derivatives 17,19-Dinoratis-15-ene-4,13,14-tricarboxylic acid, 16-(1-methylethyl), 4,13,14-trimethylester (4α,8α,12α,13β,14α) and derivatives 1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-(1-methylethyl)-, [1R-(1α,4aα,4bβ,10aα)] and derivatives 

Bromierung von Harzsäurederivaten

Zusammenfassung

Die radikalische Bromierung von1,2 und3 führt zu in der Seitenkette halogenierten Produkten. Eliminierung von HBr liefert die entsprechenden Olefine.

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Copyright information

© Springer-Verlag 1983

Authors and Affiliations

  • Ernst Haslinger
    • 1
  • Hermann Kalchhauser
    • 1
  • Harald Steindl
    • 1
  1. 1.Institut für Organische ChemieUniversität WienWienAustria

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