Monatshefte für Chemie / Chemical Monthly

, Volume 115, Issue 11, pp 1313–1317 | Cite as

Empirical correlations between solvent acidity and the optical characteristics of solvated electrons

  • Elżbieta Wagner
  • Marek K. Kalinowski
Anorganische Und Physikalische Chemie
Received:
Accepted:

Abstract

Correlations between essential characteristics of the optical absorption spectrum of the solvated electron (excitation energy, band-width) and the acceptor numbers of organic solvents are established.

Keywords

Solvated electron Optical spectrum Solvent effects 

Eine empirische Korrelation zwischen der Acidität von Lösungsmitteln und spektralen Charakteristika solvatisierter Elektronen

Zusammenfassung

Es wird eine Korrelation zwischen den wesentlichen Charakteristika des optischen Absorptionsspektrums von solvatisierten Elektronen (Anregungsenergie und Bandenbreite) und den Acceptornummern organischer Lösungsmittel gefunden.

This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Kestner N. R., Electron-Solvent and Anion-Solvent Interactions (Kevan L., Webster B. C., eds.), p. 1. Amsterdam: Elsevier. 1976.Google Scholar
  2. 2.
    Banerjee A., Simons J., J. Chem. Phys.68, 415 (1978).Google Scholar
  3. 3.
    Feng D.-F., Kevan L., Chem. Rev.80, 1 (1980).Google Scholar
  4. 4.
    Freeman G. R., J. Phys. Chem.77, 7 (1973).Google Scholar
  5. 5.
    Tremaine P. R., Dixon R. S., J. Phys. Chem.82, 224 (1978).Google Scholar
  6. 6.
    Farhataziz, Radiat. Phys. Chem.15, 503 (1980).Google Scholar
  7. 7.
    Farhataziz, Stewart G. H., Radiat. Phys. Chem.17, 145 (1981).Google Scholar
  8. 8.
    Mayer U., Pure Appl. Chem.51, 1697 (1979).Google Scholar
  9. 9.
    Gutmann V., Wychera E., Inorg. Nucl. Chem. Lett.2, 257 (1966).Google Scholar
  10. 10.
    Mayer U., Gutmann V., Gerger W., Monatsh. Chem.106, 1235 (1975).Google Scholar
  11. 11.
    Gutmann V., The Donor-Acceptor Approach to Molecular Interactions. New York: Plenum. 1978.Google Scholar
  12. 12.
    Schlick S., Narayana P. A., Kevan L., J. Chem. Phys.64, 3153 (1976).Google Scholar
  13. 13.
    Narayana M., Kevan L., J. Chem. Phys.72, 2891 (1980).Google Scholar
  14. 14.
    Delaire J. A., Delcourt M. O., Belloni J., J. Phys. Chem.84, 1186 (1980).Google Scholar
  15. 15.
    Seddon W. A., Fletcher J. W., Sophiphyn F. C., Catterall R., Can. J. Chem.55, 3356 (1977).Google Scholar
  16. 16.
    Shaede E. A., Dorfman L. M., Flynn G. J., Walker D. C., Can. J. Chem.51, 3905 (1973).Google Scholar
  17. 17.
    Leu A. D., Iha K. N., Freeman G. R., Can. J. Chem.60, 2342 (1982).Google Scholar
  18. 18.
    Dye J. L., Backer M. G., Dorfman L. M., J. Chem. Phys.52, 6251 (1970).Google Scholar
  19. 19.
    Jou F. Y., Freeman G. R., Can. J. Chem.60, 1809 (1982).Google Scholar
  20. 20.
    Gavlas J. F., Jou F. Y., Dorfman L. M., J. Phys. Chem.78, 2631 (1974).Google Scholar
  21. 21.
    Walker D. E., Klassen N. V., Gillis H. A., Chem. Phys. Lett.10, 636 (1971).Google Scholar

Copyright information

© Springer-Verlag 1984

Authors and Affiliations

  • Elżbieta Wagner
    • 1
  • Marek K. Kalinowski
    • 1
  1. 1.Department of ChemistryUniversity of WarsawWarszawaPoland

Personalised recommendations