Synergy at a distance in the synthesis of methanol over copper catalysts
Perspectives in Catalysis
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Abstract
Physical mixtures of Cu/SiO2 and ZnO/SiO2 catalysts have been studied for the synthesis of methanol from CO/CO2/H2 at 250 °C and 10 bar pressure. It is found that the activities are very much higher for the physical mixtures than would be expected from the activities of either of these two catalysts in isolation. The results suggest that the high activity of conventional Cu/ZnO/Al2O3 catalysts may arise from a synergy between the Cu and ZnO phases.
Keywords
Copper Methanol Physical Chemistry Catalysis High Activity
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References
- [1]see, e.g., J.C.J. Bart and R.P.A. Sneeden, Catalysis Today 2 (1987) 1.Google Scholar
- [2]G.J.J. Bartley and R. Burch, Applied Catalysis, in press.Google Scholar
- [3]R. Burch and R.J. Chappell, Applied Catalysis, submitted.Google Scholar
- [4]S.P.S. Andrew, Plenary Lecture (paper 12) Post Congress Symposium, 7th Intern. Congress on Catalysis, Osaka, July 1980.Google Scholar
- [5]T. Takahama, H. Oshima, A. Ueno and Y. Kotera, Applied Catalysis 5 (1983) 59.Google Scholar
- [6]W.L. Marsden, M.S. Wainwright and J.B. Friedrich, I. & E.C. Prod. Res. Dev. 19 (1980) 551.Google Scholar
- [7]A.J. Bridgewater, M.S. Wainwright, D.J. Young and J.P. Orchard, Applied Catalysis 7 (1983) 369.Google Scholar
- [8]G.C. Chinchen, P.J. Denny, D.G. Parker, G.D. Short, M.S. Spencer, K.C. Waugh and D.A. Whan, A.C.S. Symposium on Methanol Synthesis, Philadelphia, 1984.Google Scholar
- [9]G.C. Chinchen, K.C. Waugh and D.A. Whan, Applied Catalysis 25 (1986) 101.Google Scholar
- [10]T.H. Fleisch and R.L. Mieville, J. Catal. 90 (19984) 165.Google Scholar
- [11]J.B. Friedrich, M.S. Wainwright and D.J. Young, J. Catal. 80 (1983) 1.Google Scholar
- [12]J. Barbier, Th. Fortin, Ph. Courty and P. Chaumette, Bull. Soc. Chim. France (1987) 925.Google Scholar
- [13]B. Pommier and S.J. Teichner, 9th Int. Congress on Catalysis, Calgary, 1988, 2 (1988) 610.Google Scholar
- [14]P. Chaumette, Ph. Courty, J. Barbier, T. Fortin, J.C. Lavelley, C. Chauvin, A. Kiennemann, H. Idriss, R.P.A. Sneeden and B. Denise, 9th Int. Congress on Catalysis, Calgary, 1988, 2 (1988) 585.Google Scholar
- [15]M.S.W. Vong, M.A. Yates, P. Reyes, A. Perryman and P.A. Sermon, 9th Int. Congress on Catalysis, Calgary, 1988, 2 (1988) 545.Google Scholar
- [16]H. Chen, S. Wang, Y. Liao, J. Tsai, H. Zhang and K. Tsai, 9th Int. Congress on Catalysis, Calgary, 1988, 2 (1988) 537.Google Scholar
- [17]P. Ruiz and B. Delmon, Catalysis Today 3 (1988) 199.Google Scholar
- [18]W.C. Conner, G.M. Pajonk and S.J. Teichner, Advances in Catalysis 34 (1986) 1.Google Scholar
- [19]N.E. Lobashina, N.N. Savviv and I.A. Mynasnikov, Kinet. Katal. 24 (1983) 747.Google Scholar
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© J.C. Baltzer AG, Scientific Publishing CompanyJ.C. Baltzer A.G. Scientific Publishing Company 1988