Selective oxidation of cyclohexane over TS-2, a titanium silicate molecular sieve
Article
Received:
Accepted:
- 112 Downloads
- 29 Citations
Abstract
The selective oxidation of cyclohexane to cyclohexanol and cyclohexanone using hydrogen peroxide has been studied over TS-2, a titanium silicate molecular sieve with a MEL structure. The reaction is found to be catalyzed by the Ti present in the framework structure, the activity being proportional to the Ti content.
Keywords
TS-2 titanium silicates oxidation over TS-2 cyclohexane oxidation oxidation using hydrogen peroxidePreview
Unable to display preview. Download preview PDF.
References
- [1]M. Taramasso and B. Notari, U.S. Pat (1983) 4, 410, 501.Google Scholar
- [2]W.M. Meir and D.H. Olson,Atlas of Zeolite Structure Types, 2nd ed. (Butterworths, London, 1987).Google Scholar
- [3]W. Hölderich, M. Hesse and F. Näumann, Angew. Chem. Int. Ed. Engl. 27 (1988) 226.Google Scholar
- [4]B. Notari, in:Innovation in Zeolite Material Science (Stud. Surf. Sci. and Catal., Vol. 37), eds. P.J. Grobet, W.J. Mortier, E.F. Vansant and G. Schulz-Eklosf (Elsevier, Amsterdam, 1989) p. 413.Google Scholar
- [5]W.F. Hölderich, in:Zeolites as Catalysts, Sorbents and Detergent Builders (Stud. Surf. Sci. and Catal., Vol. 46), eds. H.G. Karge and J. Weitkamp (Elsevier, Amsterdam, 1989) p. 194.Google Scholar
- [6]D.R.C. Huybrechts, L. De. Bruycker and P.A. Jacobs, Nature 345 (1990) 240.Google Scholar
- [7]T. Tatsumi, M. Nakamura, S. Negishi and H-O. Tominaga, J. Chem. Soc., Chem. Commun. (1990) 476.Google Scholar
- [8]Kirk-Othmer,Encyclopaedia of Chemical Technology, 3rd ed., Vol. 18 (John Wiley and Sons, New York, 1978) p. 425.Google Scholar
- [9]J.S. Reddy, R. Kumar and P. Ratnasamy, Appl. Catal. 58 (1990) L1.Google Scholar
- [10]J.S. Reddy, S. Sivasanker and P. Ratnasamy, J. Mol. Catal., in press.Google Scholar
- [11]J.S. Reddy and S. Sivasanker, unpublished results.Google Scholar
- [12]J.S. Reddy and R. Kumar, J. Catal. 130 (1991) 440.Google Scholar
Copyright information
© J.C. Baltzer A.G. Scientific Publishing Company 1991