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Journal of Structural Chemistry

, Volume 34, Issue 1, pp 68–73 | Cite as

Consideration of vibrational anharmonicity by scaled corrections to the force constants

  • G. G. D'yachenko
Article
  • 38 Downloads

Abstract

A method is proposed for introducing scaled corrections to a harmonic force field to take account of vibrational anharmonicity. All the spectra were satisfactorily described by the introduction of only three scaling coefficients in the case of methane and ethane isotopomers.

Keywords

Physical Chemistry Methane Inorganic Chemistry Ethane Force Field 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • G. G. D'yachenko

There are no affiliations available

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