Thermochemical and thermodynamic calculation for alkylation of phenol with straight-chain α-olefins
Petroleum and Gas Processing
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Summary
- 1.
A procedure has been developed for thermochemical calculation of the reaction of phenol alkylation by olefins.
- 2.
Approximate values have been calculated for the reaction heats in the formation of o− and p−sec−monoalkylphenols in the alkylation of phenol with straight−chain α−olefins in the liquid or gas phase under standard conditions.
- 3.
It has been established experimentally that the reaction of phenol alkylation with straight−chain α−olefins, proceeding with the formation of monoalkylphenols at temperatures of 453–473°K in the liquid phase, is practically irreversible.
The calculated value for the heat of this reaction within the indicated temperature range is 20–23 kcal/mole.
Keywords
Phenol Liquid Phase Standard Condition Alkylation Thermodynamic Calculation
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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