Russian Chemical Bulletin

, Volume 44, Issue 10, pp 1963–1965 | Cite as

Photochemical reduction of carbon dioxide to formate in the coordination sphere of MoH4(PH2PCH2CH2PPh2)2

  • A. P. Pivovarov
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Abstract

UV, IR, and NMR spectra of photolysis products obtained by irradiation of MoH4(Ph2PCH2CH2PPh2)2 (1) in an atmosphere of CO2,13CO2, or C18O2 were studied. In the coordination sphere of1, photochemical reduction of carbon dioxide occurs, yielding products of formate type. Treatment of photoproducts with acids affords formaldehyde.

Key words

carbon dioxide photochemical reduction photochemistry phosphinehydride complexes of transition metals 
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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • A. P. Pivovarov
    • 1
  1. 1.Institute of Chemical Physics in ChernogolovkaRussian Academy of SciencesChernogolovka, Moscow RegionRussian Federation

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