Journal of Cluster Science

, Volume 3, Issue 2, pp 179–199 | Cite as

Synthesis, structural characterization and bonding properties of heterometallic-heterobridging cubane-type tetranuclear cluster compounds [CuMo3OS3]·I·(μ-OAc)[S2P(OC2H5)2]3·L (L=py, DMF)

  • Shao-Fang Lu
  • Jian-Quan Huang
  • Zhi-Da Chen
  • Qiang-Jin Wu
  • Wen-Zhang Chen
  • Xiao-Ying Huang
  • Zi-Xiang Huang
  • Jin-Ling Huang
  • Jia-Xi Lu
Article
Received:

Abstract

By the reaction of cluster [Mo3OS3](dtp)4(H2O) used as starting material with CuI using [3+1] mode, two novel heterometallic-heterobridging cubane-type tetranuclear cluster compounds [CuMo3OS3]·I·(μ-OAc)[S2P(OC2H5)2]3·L [(I)L=py, (II)L=DMF] [dtp=S2P(OC2H5)2; OAc=OOCCH3] containing [CuMo3OS3] core have been obtained. Compounds (I) and (II) have been characterized by IR, EPR, UV-VIS, electrochemistry and X-ray crystallography. By comparison of these two compounds with the analogous [CuMo3S4] series in the structure and molecular orbital calculation, the influence of mixed S/O bridging on the structure is discussed. It is demonstrated that the {Mo3S3} cluster ring in [Mo3OS3]4+ possesses a similar quasi-aromaticity to [Mo3S4]4+. Crystal data: for (I), space group=\(P\overline 1 \),a=13.781(8)Å,b=14.523(6)Å,c=12.098(6)Å, α=98.37(4)°, β=109.41(5)°, γ=105.00(5)°,V=2133(2)Å3,Z=2,R=0.058; for (II), space group=\(P\overline 1 \),a=13.215(4)Å,b=17.818(8)Å,c=9.873(4)Å, α=106.06(4)°, β=109.78(3)°, γ=82.00(3)°,V=2100(2)Å3,Z=2,R=0.045.

Key words

Heterometallic-heterobridging cubane-type tetranuclear cluster preparation crystal structure molecular orbital calculation quasi-aromaticity copper molybdenum 
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References

  1. 1.
    J.-Q. Huang, S.-F. Lu, M.-Y. Shang, X.-T. Lin, M.-D. Huang, D.-M. Wu, H.-H. Zhuang, J.-L. Huang, and J.-X. Lu (1987). JIEGOU HUAXUE.J. Struct. Chem. 6(4), 219.Google Scholar
  2. 2.
    J.-Q. Huang, J.-L. Huang, M.-Y. Shang, S.-F. Lu, X.-T. Lin, Y.-H. Lin, M.-D. Huang, H.-H. Zhuang, and J.-X. Lu (1988).Pure Appl. Chem. 60(8), 1185.Google Scholar
  3. 3.
    T. Shibahara, M. Yamasaki, H. Akashi, and T. Katayama (1991).Inorg. Chem. 30, 2693.Google Scholar
  4. 4.
    T. Saito, N. Yamamoto, T. Nagase, T. Tsuboi, K. Kobayashi, T. Yamagata, H. Imoto, and K. Unoura (1990).Inorg. Chem. 29, 764.Google Scholar
  5. 5.
    T. Saito, Y. Kajitani, T. Yamagata, and H. Imoto (1990).Inorg. Chem. 29, 2951.Google Scholar
  6. 6.(a)
    S.-F. Lu, M.-Y. Shang, J.-Q. Huang, J.-L. Huang, and J.-X. Lu (1988).Scientia Sinica (Series B) 31(2), 147;Google Scholar
  7. 6.(b)
    M.-D. Huang, S.-F. Lu, J.-Q. Huang, and J.-L. Huang (1987). JIEGOU HUAXUE.J. Structure. Chem. 6(1), 29.Google Scholar
  8. 7.
    Y. Zheng, M.-Y. Shang, L.-N. Zhang, J.-L. Huang, and J.-X. Lu (1983).Spect. Anal. 2, 72 (in Chinese).Google Scholar
  9. 8.
    K. Nakamoto (1978). InInfrared and Raman Spectra of Inorganic and Coordination Compounds (3rd Ed.) (John Wiley & Sons) (Chinese Edition, Translation by D.-L. Huanget al., Chemical Industry Publisher, P237, 1986).Google Scholar
  10. 9.
    The Sadtler Standard Spectra 12K, 29552K.Google Scholar
  11. 10.
    TEXSAN Version 2.0, Molecular Structure Corporation 3304 Longmire Drive College Station, TX 77840.Google Scholar
  12. 11.
    Z.-M. Wang, B. Zhang, W. Huang, J.-Q. Huang, and J.-L. Huang (1992). JIEGOU HUAXUE.J. Struct. Chem. 11(2), 127.Google Scholar
  13. 12.
    S.-F. Lu, N.-Y. Zhu, X.-T. Wu, Q.-J. Wu, and J.-X. Lu (1989).J. Mol. Struct. 197, 15.Google Scholar
  14. 13.
    X.-T. Wu, S.-F. Lu, N.-Y. Zhu, Q.-J. Wu, and J.-X. Lu (1987).Inorg. Chim. Acta. 133, 43.Google Scholar
  15. 14.
    S.-F. Lu (1991). Japan-China Seminar on Metal Cluster Complexes. Okazaki, Japan, Abstract 29.Google Scholar
  16. 15.
    S. Harris (1987).Inorg. Chem. 26, 4278.Google Scholar
  17. 16.
    R. E. Palermo, R. Singh, J. K. Bashkin, and R. H. Holm (1984).J. Am. Chem. Soc. 106, 2600.Google Scholar
  18. 17.
    M. Henary and J. I. Zink (1989).J. Am. Chem. Soc. 111, 7407.Google Scholar
  19. 18.
    X.-T. Lin, Y.-H. Lin, J.-L. Huang, and J.-Q. Huang (1985).Kexue Tongbao 7, 509 (in Chinese).Google Scholar
  20. 19.(a)
    J. A. Pople and G. A. Segal, (1966).J. Chem. Phys. 44, 3289;Google Scholar
  21. 19.(b)
    D. P. Santry and G. A. Segal (1967).J. Chem. Phys. 47, 158.Google Scholar
  22. 20.
    C.-X. Guo, Z.-Z. Wang, and A.-Q. Tang (1984). KEXUE TONGBAO29(9), 1196.Google Scholar
  23. 21.
    D. W. Clack, N. S. Hush, and J. R. Yandle (1972).J. Chem. Phys. 57, 3503.Google Scholar
  24. 22.
    P. Douglas Williams and M. D. Curtis (1986).Inorg. Chem. 25, 4562.Google Scholar

Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • Shao-Fang Lu
    • 1
  • Jian-Quan Huang
    • 1
  • Zhi-Da Chen
    • 1
  • Qiang-Jin Wu
    • 1
  • Wen-Zhang Chen
    • 1
  • Xiao-Ying Huang
    • 1
  • Zi-Xiang Huang
    • 1
  • Jin-Ling Huang
    • 1
  • Jia-Xi Lu
    • 1
  1. 1.Fujian Institute of Research on the Structure of Matter, State Key Laboratory of Structural ChemistryChinese Academy of SciencesFuzhou

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