The influence of the mercury and thallium atoms in organomercury and organothallium nitroxyl radicals on their reactivity
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Abstract
An increase is found in the reactivity of organomercury and organothallium nitroxyl mono- and biradicals of the imidazoline type in comparison with the analogous compounds without organometallic fragments. This is explained by the formation of coordination bonds N→Hg, N→Tl, and N→O→Hg.
Key words
kinetics organomercury nitroxyls organothallium nitroxyls coordination bond hydrazobenzene reduction rate constantPreview
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References
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