Advertisement

Transition Metal Chemistry

, Volume 10, Issue 6, pp 236–238 | Cite as

Cationic carbonyl complexes of ruthenium(II) and osmium(II) containing 2,2′-bipyridyl and 1,10-phenanthroline

  • K. G. S. Murthy
  • K. N. Mahendra
  • N. M. N. Gowda
  • G. K. N. Reddy
Full Papers
  • 27 Downloads

Summary

Reactions of ruthenium carbonyl complexes of the type [RuX2(CO)(Ph2RAs)3] (X=Cl or Br; R=Me or Et) with 2,2′-bipyridyl (bipy) and 1,10-phenanthroline (phen) in alcohol produce orange red cationic products of the formula [RuX(CO)(N-N)(Ph2RAs)2]ClO4 (N-N=bipy or phen). Likewise, the hydridocarbonyls of ruthenium and osmium of the type [MHX(CO)(Ph2RAs)3] (M=Ru or Os) react with bipy and phen to yield yellow cationic complexes of the composition [(MH(CO)(N-N)(Ph2RAs)2]ClO4. Structures have been assigned to all the complexes on the basis of i.r. and1 H n.m.r. spectral data.

Keywords

Alcohol Physical Chemistry Inorganic Chemistry Carbonyl Ruthenium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. (1).
    W. P. Griffith,The Chemistry of the Rarer Platinum Metals, Interscience Publishers, New York, 1967.Google Scholar
  2. (2).
    F. G. Moers, R. W. M. Ten Hoedt and J. P. Langhout,J. Inorg. Nucl. Chem., 36, 2279 (1974).Google Scholar
  3. (3).
    K. G. Srinivasamurthy, N. M. Nanje Gowda, E. G. Leelamani and G. K. N. Reddy.Proc. Indian Acad. Sci. (Chem. Sci.), 89, 101 (1980).Google Scholar
  4. (4).
    K. G. Srinivasamurthy, N. M. Nanje Gowda and G. K. N. Reddy,Proc. Indian Acad. Sci. (Chem. Sci.), 90, 451 (1981).Google Scholar
  5. (5).
    N. M. N. Gowda, S. B. Naikar and G. K. N. Reddy,Adv. Inorg. Chem. Radiochem., 28, 255 (1984).Google Scholar

Copyright information

© VCH Verlagsgesellschaft mbH 1985

Authors and Affiliations

  • K. G. S. Murthy
    • 1
  • K. N. Mahendra
    • 1
  • N. M. N. Gowda
    • 1
  • G. K. N. Reddy
    • 1
  1. 1.Department of Chemistry, Central CollegeBangalore UniversityBangaloreIndia

Personalised recommendations