Polymerization of 2-chloropentaborane using aluminum chloride
Article
Received:
Revised:
- 21 Downloads
Abstract
2-Chloropentaborane polymerized when it was heated in the presence of catalytic amounts of aluminum chloride. The polymer contained large amounts of chlorine and the volatile condensation product was primarily hydrogen.
Key words
Pentaborane 2-chloropentaborane polymer polymerization boron hydridePreview
Unable to display preview. Download preview PDF.
References
- 1.D. F. Gaines, M. W. Jorgenson, and M. A. Kulzick,J. Chem. Soc. Chem. Commun. 380 (1979).Google Scholar
- 2.K. J., Wynne and R. W. Rice,Annu. Rev. Mater. Sci. 14, 297 (1984).Google Scholar
- 3.R. N. Grimes, ed.,Metal Interactions with Boron Clusters (Plenum Press, New York, 1982).Google Scholar
- 4.D. F. Shriver and M. A. Drezdzon,The Manipulation of Air-Sensitive Compounds, 2nd ed. (John Wiley and Sons, New York, 1986).Google Scholar
- 5.D. F. Gaines and J. A. Martens,Inorg. Chem. 7, 704 (1968).Google Scholar
- 6.D. P. Eley and H. Wats,J. Chem. Soc. 1914 (1952); W. E. Jensen, Doctoral thesis (University of Wisconsin—Madison, Madison, 1982).Google Scholar
- 7.E. R. Altwicker, G. E. Ryschkewitch, A. B. Garret, and H. H. Sisler,Inorg. Chem. 3, 454 (1964).Google Scholar
- 8.G. A. Olah,Friedel-Crafts Chemistry (John Wiley and Sons, New York, 1973), p. 258.Google Scholar
- 9.G. R. Eaton and W. N. Lipscomb,NMR Studies of Boron Hydrides and Related Compounds (W. A. Benjamin, New York, 1969); L. J. Todd and A. R. Siedle,Prog. NMR Spec. 13, 87 (1979); H. Noth and B. Wrackmeyer,NMR Basic Princ. Prog. 14 (1978); D. F. Gaines, M. W. Jorgenson, and M. A. Kulzick,J. Chem. Soc. Chem. Commun. 380 (1979).Google Scholar
- 10.R. L. Parette,J. Polym. Sci. 15, 447 (1955).Google Scholar
- 11.J. A. Heppert, M. A. Kulzick, and D. F. Gaines,Inorg. Chem. 23, 14 (1984).Google Scholar
- 12.D. F. Gaines and J. A. Martens,Inorg. Chem. 7, 704 (1968).Google Scholar
- 13.D. F. Gaines, unpublished results.Google Scholar
- 14.J. A. Heppert, Doctoral thesis (University of Wisconsin—Madison, Madison, 1982), pp. 16–17.Google Scholar
- 15.D. F. Gaines, unpublished results.Google Scholar
Copyright information
© Plenum Publishing Corporation 1993