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Colloid and Polymer Science

, Volume 274, Issue 1, pp 49–58 | Cite as

Markov chain model of mixed surfactant systems

I. New expression for the non-ideal interaction parameter
  • G. S. Georgiev
Original Contribution

Abstract

A new model of mixed surfactant systems have been developed in the work presented. It includes two parameters only connected directly with the Gibbs free energy of the surfactant aggregation. They can be determined using both the aggregation equilibrium constant values or the phase composition data. It has been shown also the relation between these new parameters and the same of the regular solution approximation and the alternative models. The possibility to describe the available experimental information about the micelle composition as a function of the singly dispersed surfactant mixture composition better than by the other models has been shown also.

Key words

Mixed surfactant system non-ideal interaction parameter regular solution approximation model Markov chain model conditional probability transition matrix 

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Copyright information

© Steinkopff Verlag 1996

Authors and Affiliations

  • G. S. Georgiev
    • 1
  1. 1.Department of ChemistryUniversity of SofiaSofiaBulgaria

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