Dielectric relaxation studies of aqueous N,N-dimethylformamide using a picosecond time domain technique
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- Kumbharkhane, A.C., Puranik, S.M. & Mehrotra, S.C. J Solution Chem (1993) 22: 219. doi:10.1007/BF00649245
The dielectric relaxation studies of N,N-dimethylformamide at thirteen concentration in aqueous solutions have been carried out using a time domain reflectometry technique in the frequency range 10 MHz to 10 GHz. The dielectric parameters and excess dielectric properties have also been determined from 5 to 40°C. The Luzar theory was applied to compute the cross correlation terms for the mixture. It adequately reproduces the experimental values of the static dielectric constants. The Bruggeman model for the nonlinear case has been fitted to the dielectric data for mixtures.
Key WordsN,N-dimethyformamide time domain technique dielectric relaxation excess properties cross correlation terms nonlinear Bruggeman model thermodynamic properties
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