Journal of Solution Chemistry

, Volume 9, Issue 2, pp 129–139 | Cite as

Triple ion formation in solutions of alkaline sulfocyanides

  • P. Bacelon
  • J. Corset
  • C. de Loze


Through the infrared and Raman spectra of alkaline sulfocyanides in high-and low-polarity media, nitromethane (CH3NO2) and tetrahydrofuran (THF), triple cations and triple anions may be characterized. The formation of these species at the expense of ion pairs or more aggregated species such as dimers is discussed taking into account cation solvation, anion solvation, and the influence of cation-anion interaction.

Key words

Infrared-Raman study ionic association-solution triple ions aprotic solvents nitromethane tetrahydrofuran alkaline and tetraalkylammonium sulfocyanides 


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  1. 1.
    R. M. Fuoss and C. A. Kraus,J. Am. Chem. Soc. 55, 2387 (1933).Google Scholar
  2. 2.
    A. Regis and J. Corset,Chem. Phys. Lett. 32, 462, (1975).Google Scholar
  3. 3.
    C. Cambillau, G. Bram, J. Corset, C. Riche, and C. Pascard-Billy,Nouv. J. Chim. 3, 9 (1979).Google Scholar
  4. 4.
    A. Loupy and J. Corset,C. R. Acad. Sci. Ser. C 279, 713 (1974);J. Solution Chem. 5, 817 (1976).Google Scholar
  5. 5.
    C. Menard, B. Wojtkowiak, and M. Chabanel,Bull. Soc. Chim. Belg. 81, 241 (1972).Google Scholar
  6. 6.
    D. Paoli, M. Luçon, and M. Chabanel,Spectrochim. Acta Part A 34, 1087 (1978).Google Scholar
  7. 7.
    D. Paoli, M. Luçon, and M. Chabanel,Spectrochim. Acta Part A 35, 593 (1979).Google Scholar
  8. 8.
    J. Vaes, M. Chabanel, and M. L. Martin,J. Phys. Chem. 82, 2420 (1973).Google Scholar
  9. 9.
    P. Bacelon, C. de Loze, and J. Corset, Euchem Conference on Ion-Molecule Interactions in Nonaqueous Media, Louvain, Belgique (1978), p. 43.Google Scholar
  10. 10.
    M. Chabanel and M. Luçon, VI International Conference on Nonaqueous Solutions, Waterloo (1978), p. 36.Google Scholar
  11. 11.
    J. O. Besenhard and C. Eichinger,J. Electroanal. Chem. 68, 1 (1976).Google Scholar
  12. 12.
    R. Jasinski,Electrochem. Tech. 6, 28 (1968).Google Scholar
  13. 13.
    U. Mayer, V. Gutmann, and W. Gerger,Monatsh. Chem. 106, 1235 (1975).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • P. Bacelon
    • 1
  • J. Corset
    • 1
  • C. de Loze
    • 1
  1. 1.Laboratoire de Spectrochimie Infrarouge et RamanCNRSThiaisFrance

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