Synthesis, stereochemistry, and isomeric transformations of 4-aryl-5-aroyl-2-methylthio-2-imidazolines
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Abstract
The corresponding 4-aryl-5-aroyl-2-methylthio-2-imidazolines were obtained by the reaction of complexes of cis- and trans-3-aroylaziridines and boron trifluoride with methyl thiocyanate. It is shown on the basis of spectral data that the aziridine ring is opened regiospecifically at the C(2) atom and stereospecifically with inversion of the configuration.
Keywords
Methyl Organic Chemistry Boron Spectral Data Thiocyanate
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© Plenum Publishing Corporation 1989