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Synthesis of 5-alkenyl-1,3-dioxanes


Cyclic acetals containing alkenyl groups were obtained from 5-methyl-5-acyl-1,3-dioxane. The 1,3-dioxane fragment does not interfere in reduction of the carbonyl group, nor in participation of the carbonyl group in Wittig and Grignard reactions.

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Literature Cited

  1. 1.

    D. L. Rakhmankulof, R. A. Karakhanov, S. S. Zlotskii, E. A. Kantor, U. B. Imashev, and A. M. Syrkin, “Chemistry and technology of 1,3-dioxacyclanes,”Ref. Zh. Khim., Tekhnol. Org. Veshch.,5, 279 (1979).

  2. 2.

    D. L. Rakhmankulov, S. S. Zlotskii, M. G. Safarov, et al.,Mechanisms of Reactions of Acetals [in Russian], Khimiya, Moscow (1987), p. 292.

  3. 3.

    V. N. Saprygina, S. S. Zlotskii, and D. L. Rakhmankulov,Izv. Vyssh. Uchebn., Zaved., Khim. Khim. Tekhnol.,29, 110 (1986).

  4. 4.

    B. Wessen and L.-O. Ryrfors,Acta Chem. Scand.,22, 2071 (1968).

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 37–39, January, 1991.

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Lesnikova, E.T., Zlotskii, S.S. & Rakhmankulov, D.L. Synthesis of 5-alkenyl-1,3-dioxanes. Chem Heterocycl Compd 27, 30–32 (1991).

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  • Acetal
  • Organic Chemistry
  • Carbonyl
  • Carbonyl Group
  • Dioxane