The synthesis has been effected of derivatives of MDP having a spacer with an amino or carboxy group. The final stage of the synthesis was the condensation of Boc-L-Ala-D-iGln with 6-aminohexanol (followed by the two-stage replacement of the hydroxy by an azido group) or with benzyl 6-aminohexanoate.
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Kur'yanov, V.O., Zhelobetskaya, T.F., Zemlyakov, A.E. et al. Synthesis of ω-amino- and ω-carboxyalkylamides of N-acetylmuramoyl-L-alanyl-D-isoglutamine. Chem Nat Compd 29, 103–106 (1993). https://doi.org/10.1007/BF00631033
- Organic Chemistry
- Final Stage
- Carboxy Group