Advertisement

Transition Metal Chemistry

, Volume 9, Issue 7, pp 247–250 | Cite as

Metal complexes of sulphur-nitrogen chelating agents. Part 14. Nickel(II), palladium(II), copper(II), cobalt(II), and cobalt(III) complexes of the tetradentate schiff bases having ONNS donor sites

  • Santosh K. Mondal
  • Parimal Paul
  • Rita Roy
  • Kamalaksha Nag
Full Papers

Summary

Complexes of nickel(II), palladium(II), copper(II), cobalt(II), and cobalt(III) with methyl-2-(β-salicylaldiminoethyl)-cyclopent-1-en-dithiocarboxylate (H2L1) and methyl-2-(β-salicylaldiminoisopropyl)cyclopent-1-en-dithiocarboxylate (H2L2) have been prepared. They contain the donor sites ONNS. The metal(II) ions from neutral, monomeric square planar chelate complexes. The cobalt(III) complexes [CoL1-(H2O)2]X (X=Cl or ClO4) appear to betrans-diaqua-species. All compounds have been characterized by a number of physico-chemical methods.

Keywords

Copper Physical Chemistry Nickel Cobalt Inorganic Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. (1).
    S. G. Murray and F. R. Hartley,Chem. Rev. 81, 365 (1981).Google Scholar
  2. (2).
    M. Akbar Ali and S. E. Livingstone,Coord. Chem. Rev., 13, 101 (1974).Google Scholar
  3. (3).
    R. Morassi, I. Bertini and L. Sacconi,Coord. Chem. Rev., 11, 343 (1973).Google Scholar
  4. (4).
    C. A. McAuliffe,Adv. Inorg. Radiochem., 17, 165 (1970).Google Scholar
  5. (5).
    R. H. Holm, G. W. Everett, Jr. and A. Chakravorty,Progr. Inorg. Chem., 7, 83 (1966).Google Scholar
  6. (6).
    S. Yamada,Coord. Chem. Rev., 1, 415 (1966).Google Scholar
  7. (7).
    E. Sinn and C. M. Harris,Coord. Chem. Rev., 4, 391 (1969).Google Scholar
  8. (8).
    M. D. Hobday and T. D. Smith,Coord. Chem. Rev., 9, 311 (1972–73).Google Scholar
  9. (9).
    R. D. Jones, D. A. Summerville and F. Basolo,Chem. Rev., 79, 135 (1979).Google Scholar
  10. (10).
    C. Dawl, W. P. Schlapfer and A. V. Zelewsky,Struct. Bonding (Berlin), 36, 129 (1979).Google Scholar
  11. (11).
    S. K. Mondal, D. S. Joarder and K. Nag,Inorg. Chem. 17, 191 (1978).Google Scholar
  12. (12).
    R. Roy, P. Paul and K. Nag,Transition Met. Chem., in press.Google Scholar
  13. (13).
    R. D. Bereman, M. R. Churchill and G. Shields,Inorg. Chem., 18, 3117 (1979).Google Scholar
  14. (14).
    R. D. Bereman, G. Shields, J. Bordner and J. R. Dorfman,Inorg. Chem., 20, 2165 (1981).Google Scholar
  15. (15).
    R. D. Bereman, D. P. Rillema, P. McCarthy and G. Shields,J. Inorg. Biochem., 16, 47 (1982).Google Scholar
  16. (16).
    P. R. Blum, R. M. C. Wei and S. C. Cummings,Inorg. Chem., 13, 450 (1974).Google Scholar
  17. (17).
    L. S. Chen and S. C. Cummings,Inorg. Chem., 17, 2358 (1978).Google Scholar
  18. (18).
    M. F. Corrigan and B. O. West,Aust. J. Chem., 29, 1413 (1976).Google Scholar
  19. (19).
    P. J. Marini, K. S. Murray and B. O. West,J. Chem. Soc., Dalton Trans., 143, (1983).Google Scholar
  20. (20).
    R. C. Coombes, J. P. Costes and D. E. Fenton,Inorg. Chim. Acta Lett., 77, L173 (1983).Google Scholar
  21. (21).
    R. Roy, S. K. Mandal and K. Nag,J. Chem. Soc., Dalton Trans., 1935 (1983).Google Scholar
  22. (22).
    R. Roy, M. Chaudhury, S. K. Mandal and K. Nag,J. Chem.Soc., Dalton Trans., in press.Google Scholar
  23. (23).
    P. Paul, R. Roy and K. Nag,Indian J. Chem., Sect A, communicated.Google Scholar
  24. (24).
    S. K. Mandal and K. Nag,Inorg. Chem., 22, 2567 (1983);J. Chem. Soc., Dalton Trans., 2429 (1983).Google Scholar
  25. (25).
    D. Hall and J. N. Waters,J. Chem. Soc., 2444 (1960).Google Scholar
  26. (26).
    R. Dingle,Acta Chem. Scand., 20, 33 (1966).Google Scholar
  27. (27).
    S. J. Gruber, C. M. Harris and E. Sinn,Inorg. Chem., 7, 268 (1968).Google Scholar
  28. (28).
    G. O. Carlisle and W. E. Hatfield,Inorg. Nucl. Chem. Lett., 6, 633 (1970).Google Scholar
  29. (29).
    S. K. Mandal and K. Nag,J. Chem. Soc., Dalton Trans., in press.Google Scholar
  30. (30).
    W. P. Schaeffer and R. E. Marsh,Acta Crystallogr. Sect. B, 25, 1675 (1969).Google Scholar
  31. (31).
    R. DeIasi, S. L. Holt and B. Port,Inorg. Chem., 10, 1498 (1971).Google Scholar
  32. (32).
    B. J. Hathaway and D. E. Billing,Coord. Chem. Rev., 5, 143 (1970).Google Scholar
  33. (33).
    M. A. Hitchman,Inorg. Chem., 16, 1985 (1977);Inorg. Chim. Acta, 26, 237 (1978).Google Scholar
  34. (34).
    B. R. McGarvey,Can. J. Chem., 53, 2498 (1975).Google Scholar
  35. (35).
    F. Cariati, F. Morazzoni, C. Busetto, G. del Piero and A. Zazzetta,J. Chem. Soc., Dalton Trans., 342 (1976).Google Scholar
  36. (36).
    A. B. P. Lever,Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1968.Google Scholar
  37. (37).
    M. I. Scullen and H. C. Allen, Jr.,J. Coord. Chem., 4, 255 (1975).Google Scholar

Copyright information

© Verlag Chemie GmbH 1984

Authors and Affiliations

  • Santosh K. Mondal
    • 1
  • Parimal Paul
    • 1
  • Rita Roy
    • 1
  • Kamalaksha Nag
    • 1
  1. 1.Department of Inorganic ChemistryIndian Association for the Cultivation of ScienceCalcuttaIndia

Personalised recommendations