The hydrothermal system of Volcan Puracé, Colombia
- 94 Downloads
- 15 Citations
Abstract
This paper presents chemical and isotopic data for thermal waters, gases and S deposits from Volcan Puracé (summit elevation ∼4600 m) in SW Colombia. Hot gas discharges from fumaroles in and around the summit crater, and thermal waters discharge from three areas on its flanks. The waters from all areas have δD values of-75±1, indicating a single recharge area at high elevation on the volcano. Aircorrected values of3He/4He in thermal waters range from 3.8 to 6.7 RA, and approach those for crater fumarole gas (6.1–7.1 RA), indicating widespread addition of magmatic volatiles. An economic S deposit (El Vinagre) is being mined in the Rio Vinagre fault zone at 3600 m elevation. Sulfur isotopic data are consistent with a magmatic origin for S species in thermal waters and gases, and for the S ore deposit. Isotopic equilibration between S species may have occurred at 220±40°C, which overlaps possible equilibration temperatures (170±40°C) determined by a variety of other geothermometers for neutral thermal waters. Apparent CH4−CO2 equilibration temperatures for gases from thermal springs (400±50°C) and crater fumaroles (520±60°C) reflect higher temperatures deeper in the system. Hot magmatic gas ascending through the Rio Vinagre fault zone is though to have precipitated S and generated thermal waters by interaction with descending meteoric waters.
Key words
Volcan Puracé Colombia hydrothermal system volcanic gases He isotopes S isotopesPreview
Unable to display preview. Download preview PDF.
References
- Bottinga Y (1968) Calculation of fractionation factors for carbon and oxygen exchange in the system calcite-carbon dioxide-water. J Phys Chem 72:800–808Google Scholar
- Chiba H, Sakai H (1985) Oxygen isotope exchange rate between dissolved sulfate and water at hydrothermal temperatures. Geochim Cosmochim Acta 49:993–1000Google Scholar
- Colony WE, Nordlie BE (1973) Liquid sulfur at Volcan Azufre, Galapagos Islands. Econ Geol 68:371–380Google Scholar
- Craig H (1961) Isotopic variations in meteoric waters. Science 133:1702–1703Google Scholar
- Ellis AJ, Mahon WAJ (1977) Chemistry and geothermal systems. Academic Press, New York, 392 ppGoogle Scholar
- Fouillac C, Michard G (1981) Sodium/lithium ratio in water applied to geothermometry of geothermal reservoirs. Geothermics 10:55–70Google Scholar
- Fournier RO (1981) Application of water geochemistry to geothermal exploration and reservoir engineering. In: Rybach L, Muffler LJP (eds) Geothermal systems: principles and case histories. John Wiley & Sons, New York, 109–143Google Scholar
- Giggenbach WF (1988) Geothermal solute equilibria: derivation of Na−K−Mg−Ca geoindicators. Geochim Cosmochim Acta 52:2749–2765Google Scholar
- Giggenbach WF (1992) The composition of gases in geothermal and volcanic systems as a function of tectonic setting. In: Kharaka YI, Maest AS (eds) Water-rock interactions, vol. 2. AA Balkema, Rotterdam, 873–878Google Scholar
- Giggenbach WF, Goguel RL (1989) Collection and analysis of geothermal and volcanic water and gas discharges. Dept Sci Ind Res Report CD-2401, Petone, New Zealand, 53 ppGoogle Scholar
- Giggenbach WF, Matsuo S (1991) Evaluation of results from second and third IAVCEI field workshops on volcanic gases, Mt. Usu, Japan and White Island, New Zealand. Appl Geochem 6:125–141Google Scholar
- Giggenbach WF, Garcia PN, Londoño CA, Rodriguez VL, Rojas GN, Calvache VML (1990) The chemistry of fumarolic vapor and thermal-spring discharges from the Nevado del Ruiz volcanic-magmatic-hydrothermal system, Colombia. J Volcanol Geotherm Res 42:13–39Google Scholar
- Hedenquist JW (1987) Mineralization associated with volcanic-related hydrothermal systems in the Circum-Pacific Basin. In: Horn MK (ed), Trans Fourth Circum-Pacific Energy Min Resources Conf. 513–524, SingaporeGoogle Scholar
- Holt BD (1977) Preparation of carbon dioxide from sulfates, sulfur dioxide, air, and water for determination of oxygen isotope ratio. Anal Chem 49:1664–1667Google Scholar
- Kharaka Y, Mariner RH (1989) Chemical geothermometers and their application to formation waters from sedimentary basins. In: Naeser ND, McCulloh TH (eds), Thermal history of sedimentary basins: methods and case histories, Springer-Verlag, New York, 99–117Google Scholar
- Kiyosu Y, Kurahashi M (1983) Origin of sulfur species in acid sulfate-chloride thermal waters, northeastern Japan. Geochim Cosmochim Acta 47:1237–1245Google Scholar
- Koller B, Aucott J (1986) Algunas observaciones sobre los posibles cambios morfologicos del Volcan Puracé y geoquimica de sus aquas termales despues del sismo del 31 de Marzo de 1983. In: El Sismo de Popayán del 31 de Marzo de 1983, Inst Nac Inv Geol-Min (INGEOMINAS) Bogota, ColombiaGoogle Scholar
- Matsuo S, Suzuki M, Mizutani Y (1978) Nitrogen to argon ratio in volcanic gases. In: Alexander EC, Ozima M (eds) Terrestrial rare gases. Cent Acad Publ, Japan, 17–25Google Scholar
- McCrea JM (1950) On the isotope chemistry of carbonates and a paleotemperature scale. J Chem Phys 18:849–857Google Scholar
- McKenzie WF, Truesdell AH (1977) Geothermal reservoir temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes. Geothermics 5:51–61Google Scholar
- Megyesi I (1962) Estudios sobra los depositos de azufre en la mina de ‘El Vinagre’, Puracé. Biol Geol 10:109–160. Serv Geol Nac, Bogota, Colombia.Google Scholar
- Ohmoto H, Lasaga AC (1982) Kinetics of reactions between aqueous sulfates and sulfides in hydrothermal systems. Geochim Cosmochim Acta 46:1727–1746Google Scholar
- Oppenheim V (1950) The Volcan Puracé. Am J Sci 248:171–179Google Scholar
- Oppenheimer C (1992) Sulphur eruptions at Volcán Poás, Costa Rica. J Volcanol Geotherm Res 49:1–21Google Scholar
- Oppenheimer C, Stevenson D (1989) Liquid sulphur lakes at Poás volcano. Nature 342:790–793Google Scholar
- Ozima M, Podosek FA (1983) Noble gas geochemistry. Cambridge University Press, Cambridge, 367 ppGoogle Scholar
- Rowe GL, Brantley SL, Fernandez M, Fernandez JF, Borgia A, Barquero J (1992) Fluid-volcano interaction in an active stratovolcano: the crater lake system of Poás volcano, Costa Rica. J Volcanol Geotherm Res 49:23–51Google Scholar
- Sano Y, Nakamura Y, Wakita H, Urabe A, Tominaga T (1984) Helium-3 emission related to volcanic activity. Science 224:150–151Google Scholar
- Sano Y, Wakita H, Williams SN (1990) Helium-isotope systematics at Nevado del Ruiz volcano, Colombia: implications for the volcanic hydrothermal system. J Volcanol Geotherm Res 42:41–52Google Scholar
- Simkin T, Siebert L, McClelland L, Bridge D, Newhall C, Latter JH (1981) Volcanoes of the world. Smithsonian Institution. Hutchinson Ross Co. Stroudsburg, PA, 1–213Google Scholar
- Stoffregen R (1987) Genesis of acid-sulfate alteration and Au−Cu−Ag mineralization at Summitville, Colorado. Econ Geol 82:1575–1591Google Scholar
- Sturchio NC, Williams SN, Garcia N, Londono A (1988) The hydrothermal system of Nevado del Ruiz volcano, Colombia. Bull Volcanol 50:399–412Google Scholar
- Theilig E (1982) A primer on sulfur for the planetary geologist. NASA Contr Rept 3594, 34 pGoogle Scholar
- Thode HG, Cragg CB, Hulston JR, Rees CE (1971) Sulfur isotope exchange between sulfur dioxide and hydrogen sulfide. Geochim Cosmochim Acta 35:35–45Google Scholar
- Williams SN, Sano Y, Wakita H (1987) Helium-3 emissions from Nevado del Ruiz volcano, Colombia. Geophys Res Lett 14:1039–1041Google Scholar
- Williams SN, Sturchio NC, Calvache ML, Mendez F, Londoño A, Garcia N (1990) Sulfur dioxide from Nevado del Ruiz volcano, Colombia: total flux and isotopic constraints on its origin. J Volcanol Geotherm Res 42:53–68Google Scholar