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Synthesis, characterisation and solid state thermal behaviour of nickel(II) diamine complexes

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Summary

[NiL2X2] (L =N,N′-dimethyl-1,2-ethanediamine; X = Cl, CF3CO 2 , CC13CO 2 and CBr3CO 2 ), [NiL2C2O4] · H2O and [NiL2X2] · 2 H2O (X = Br, 0.5 SO 4 2− and 0.5 SeO 4 ) have been synthesised and their thermal studies carried out. Thermally induced phase transition phenomena are noticed in [NiL2X2] (X = CF3CO 2 and CCl3CO 2 ) and their probable mechanisms are described. [NiL2X2] (X = Br, 0.5 SO 4 2− and 0.5 SeO 4 2− ) and [NiLX2] (X = Cl, 0.5 C2O 4 2− and 0.5 SO 4 2− ) have been prepared by solid state pyrolysis from the respective parent diamine complexes. [NiL2X2] have been made in solid state by temperature arrest technique from [NiL2(CX3CO2)2] (X = Cl and Br).

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Correspondence to Nirmalendu Ray Chaudhuri.

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Ghosh, A., De, G. & Ray Chaudhuri, N. Synthesis, characterisation and solid state thermal behaviour of nickel(II) diamine complexes. Transition Met Chem 11, 81–86 (1986). https://doi.org/10.1007/BF00623759

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Keywords

  • Nickel
  • Phase Transition
  • Pyrolysis
  • Solid State
  • Diamine