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Thiocarboxamide complexes of rhodium, copper, palladium and platinum. The synthesis of [CuX(C4H4NCSNHCO2Et)(MPh3)2] (X = Cl or Br; M = As or P), [RhCl(MeC6H4CSNHCO2Et)2(PPh3)] and [M(MeC6H4CSNHCO2Et)2(PPh3)2] (M = Pd or Pt)

Summary

Reaction ofN-ethoxycarbonylpyrrole-1-thiocarboxamide (EPTH) with [CuX(MPh3)3] yields [CuX(EPTH)(MPh3)2] (X = Cl or Br; M = As or P) and ofN-ethoxycarbonyltoluene-4-thiocarboxamide (ETTH) with [RhICl(PPh3)3], [Pd0(PPh3)4] and [Pt0(PPh3)4] yields [RhICl(ETTH)2(PPh3)], [Pd0(ETTH)2(PPh3)2] and [Pt0(ETTH)2(PPh3)2], respectively. The complexes have been characterised by analytical, i.r., electronic and n.m.r. spectral and magnetic measurements. All are tetrahedral except [RhCl(ETTH)2(PPh3)], which is square planar (trans).

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Correspondence to Sheo K. Dikshit.

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Chauhan, V., Dikshit, S.K. Thiocarboxamide complexes of rhodium, copper, palladium and platinum. The synthesis of [CuX(C4H4NCSNHCO2Et)(MPh3)2] (X = Cl or Br; M = As or P), [RhCl(MeC6H4CSNHCO2Et)2(PPh3)] and [M(MeC6H4CSNHCO2Et)2(PPh3)2] (M = Pd or Pt). Transition Met Chem 11, 403–405 (1986). https://doi.org/10.1007/BF00623416

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Keywords

  • Copper
  • Physical Chemistry
  • Platinum
  • Inorganic Chemistry
  • Palladium