Transition Metal Chemistry

, Volume 10, Issue 7, pp 255–258 | Cite as

Transition metal chemistry of oxime — Containing ligands, Part XXVIII; manganese(II) complexes of 2,6-diacetylpyridine dioxime

  • Madan Mohan
  • Munesh Kumar
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Summary

Complexes of manganese(II) with the tridentate oxime ligand 2,6-diacetylpyridine dioxime (H2dapd) have been synthesized and characterized. The complexes [Mn(H2dapd)X2] are pentacoordinate for X = Cl, Br or I but apparently octahedralvia bridging anions for X = NCS or NCSe. The complex [Mn(H2dapd)(NO3)2] adopts an octahedral structure involving monodentate and bidentate coordination of nitro groups. The complexes [Mn(H2dapd)2]X2 (X = Cl, Br, I, NO3, NCS or NCSe) involve an octahedral cation.

Keywords

Physical Chemistry Manganese Inorganic Chemistry Oxime Nitro Group 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© VCH Verlagsgesellschaft mbH 1985

Authors and Affiliations

  • Madan Mohan
    • 1
  • Munesh Kumar
    • 1
  1. 1.Department of ChemistryN.R.E.C. CollegeKhurja-203131 (U.P.)India

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