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Photochemical studies of the MoVI citric acid complex Mo2O5OH(H2O)(C6H5O7)2−

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Summary

The bridged dimeric MoVI complexes of citric acid M2[Mo2O5OH(H2O)(C6H5O7)] · 0.5 H2O, M=K+, NH 4 + , have been synthesized. In the solid state they undergo an irreversible photochemical reaction to yield CO2, MoV species and acetone dicarboxylic acid. In aqueous solution the ligand decomposition proceeds further to yield acetone as the main product. The results are compared with other related studies.

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Correspondence to Peter A. Williams.

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Pedrosa de Jesus, J.D., de Deus Farropas, M., O'Brien, P. et al. Photochemical studies of the MoVI citric acid complex Mo2O5OH(H2O)(C6H5O7)2− . Transition Met Chem 8, 193–195 (1983). https://doi.org/10.1007/BF00620685

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Keywords

  • Physical Chemistry
  • Aqueous Solution
  • Acetone
  • Inorganic Chemistry
  • Solid State