Transition Metal Chemistry

, Volume 10, Issue 10, pp 385–386 | Cite as

Reactions of theortho-metallated rhodium(I) complex of the formula Rh[P(OC6H4)(OPh)2][P(OPh)3]3 with HX molecules

  • Anna M. Trzeciak
  • Józef J. Ziołkowski
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Summary

Theortho-metallated complex [RhP3Pt] [P=P(OPh)3, P′=P(OC6H4)(OPh)2] was obtained in the reaction of [RhP4]ClO4 with KOH. It reacts easily with proton donors HX (X=ClO4, F, Cl, SCN, or acetylacetonate) to produce complexes [RhP3X] when X is a strong donor. If X is a weaker donor (X=ClO4 or F), pentacoordinate compounds of the type [PhP4X] are formed. [RhP3P′] reacts with acetylacetone (Hacac) to produce [Rh(acac)P2].

Keywords

Physical Chemistry Inorganic Chemistry Acac Rhodium Acetylacetonate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© VCH Verlagsgesellschaft mbH 1985

Authors and Affiliations

  • Anna M. Trzeciak
    • 1
  • Józef J. Ziołkowski
    • 1
  1. 1.Institute of ChemistryUniversity of WrocławWrocławPoland

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