Transition Metal Chemistry

, Volume 9, Issue 3, pp 109–112

Structure and properties of anthranilato- andN-phenylanthranilatorhodium(I) complexes withcis, cis-cycloocta-1,5-diene

  • Andrzej F. Borowski
  • Irena Rajca
Full Papers

Summary

Reaction products of [{RhCl(η-COD)}2] (COD=cycloocta-1,5-diene) with sodium salts of anthranilic andN-phenylanthranilic acid have been isolated and their structures and catalytic activities investigated. A monomeric square-planar structure with O-Rh-N bonds is postulated for the anthranilate complex, and a dimeric structure, with carboxylate bridges and without binding of the β-amine nitrogen to rhodium, is postulated for theN-phenylanthranilate. Catalytic activities in hydrogenation of some alkenes, dienes, aromatic and heteroaromatic compounds have been investigated at ambient temperature and pressure. The stability of the complexes under hydrogenation conditions is low and complete saturation has been achieved only forn-alkenes and dienes.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. (1).
    V. A. Avilov, O. N. Eremenko, O. N. Efimov, A. G. Ovcharenko, M. L. Khidekel and P. S. Chekrii,USSR Pat. 215 200.Google Scholar
  2. (2).
    M. L. Khidekel, O. N. Efimov and A. G. Ovcharenko,USSR Pat. 271 501.Google Scholar
  3. (3).
    O. N. Efimov, M. L. Khidekel, V. A. Avilov, P. S. Chekrii, O. N. Eremenko and A. G. Ovcharenko,J. Gen. Chem. USSR, 38, 2581 (1968).Google Scholar
  4. (4).
    O. N. Efimov, O. N. Eremenko, A. G. Ovcharenko, M. L. Khidekel and P. S. Chekrii,Bull. Acad. Sci. USSR, Chem. Sect., 778 (1969).Google Scholar
  5. (5).
    I. Rajca, A. Borowski and A. Rajca,Proc. Symp. Rhodium Homog. Catal, Veszprém, 1978, p. 58.Google Scholar
  6. (6).
    I. Rajca, A. Borowski and A. Marzec,Erdöl u. Kohle, 35, 36 (1982).Google Scholar
  7. (7).
    I. Rajca,Polish J. Chem., 55, 775 (1981).Google Scholar
  8. (8).
    V. A. Avilov, Yu. G. Borod'ko, V. B. Panov, M. L. Khidekel and P. S. Chekrii,Kinet. Catal. USSR, 9, 582 (1968).Google Scholar
  9. (9).
    A. F. Borowski,Transition Met. Chem., 8, 266 (1983).Google Scholar
  10. (10).
    A. G. Hill and C. Curran,J. Phys. Chem., 64, 1519 (1960).Google Scholar
  11. (11).
    G. S. Shephard and D. A. Thornton,J. Mol. Struct., 16, 321 (1973).Google Scholar
  12. (12).
    E. Kwaskowska-Chçć and J. J. Ziólkowski,Transition Met. Chem., 8, 103 (1983).Google Scholar
  13. (13).
    K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd Edit., Wiley-Interscience, New York, 1978, p. 232.Google Scholar
  14. (14).
    F. Pruchnik and K. Wajda,Inorg. Chim. Acta., 40, 203 (1980).Google Scholar
  15. (15).
    J. Chatt and L. M. Venanzi,J. Chem. Soc., 4735 (1957).Google Scholar
  16. (16).
    P. de Meester and A. C. Skapski, personal communication.Google Scholar
  17. (17).
    A. M. Trzeciak, T. Lis and J. J. Ziölkowski, prepared for publication.Google Scholar
  18. (18).
    I. Pajorska-Rajca,Ph. D. Dissertation, Petroleum and Coal Chemistry Dept., Polish Academy of Sciences, Gliwice, 1979.Google Scholar
  19. (19).
    M. A. Bennett, R. J. H. Clark and D. L. Milner,Inorg. Chem., 6, 1647 (1967).Google Scholar

Copyright information

© Verlag Chemie GmbH 1984

Authors and Affiliations

  • Andrzej F. Borowski
    • 1
  • Irena Rajca
    • 1
  1. 1.Petroleum and Coal Chemistry DepartmentPolish Academy of SciencesGliwicePoland

Personalised recommendations