Transition Metal Chemistry

, Volume 9, Issue 9, pp 342–344 | Cite as

Cobalt(III) complexes with aminothiolates

  • Heribert Barrera
  • Joan Suades
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Summary

This article describes some complexes of cobalt(III) with γ-mercaptopropylamine,N, N-dimethyl-γ-mercaptopropylamme andN,N-dimethyl-β-mercaptoethylamine. The compounds are of stoichiometry [Co(ligand)3], [Co3(ligand)6]X (X=Cl or Br) and [Co(ligand)3]X3 (X=Cl or ClO4).

γ-Mercaptopropylamine yields both chelated and non-chelated compounds while theN,N-dimethyl derivatives yield only non-chelated complexes. This behaviour contrasts with the results obtained with nickel(II).

Keywords

Physical Chemistry Nickel Cobalt Inorganic Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Verlag Chemie GmbH 1984

Authors and Affiliations

  • Heribert Barrera
    • 1
  • Joan Suades
    • 1
  1. 1.Departament de Química InorgànicaUniversität Autònoma de BarcelonaSpain

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